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Ch.5 - Periodicity & Electronic Structure of Atoms
Chapter 5, Problem 137

(c) What is the velocity of an electron with a de Broglie wavelength equal to (b)?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

de Broglie Wavelength

The de Broglie wavelength is a fundamental concept in quantum mechanics that relates the wavelength of a particle to its momentum. It is given by the formula λ = h/p, where λ is the wavelength, h is Planck's constant, and p is the momentum of the particle. This concept illustrates the wave-particle duality of matter, indicating that particles like electrons exhibit both wave-like and particle-like properties.
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Momentum of an Electron

Momentum is a vector quantity defined as the product of an object's mass and its velocity (p = mv). For an electron, which has a very small mass, its momentum can significantly influence its behavior in quantum mechanics. Understanding how to calculate the momentum of an electron is essential for determining its velocity when given its de Broglie wavelength.
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Velocity Calculation

Velocity is defined as the rate of change of an object's position with respect to time and is calculated as v = p/m, where p is momentum and m is mass. In the context of the de Broglie wavelength, once the momentum of the electron is determined using its wavelength, the velocity can be easily calculated. This relationship is crucial for solving problems involving the motion of quantum particles.
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Related Practice
Textbook Question
Assume that the rules for quantum numbers are different and that the spin quantum number ms can have any of three values, ms = -1/2, 0, +1/2, while all other rules remain the same. (a) Draw an orbital-filling diagram for the element with Z = 25, showing the individual electrons in the outer-most subshell as up arrows, down arrows, or 0. How many partially filled orbitals does the element have?
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Textbook Question

A minimum energy of 7.21⨉10-19 J is required to produce the photoelectric effect in chromium metal. (a) What is the minimum frequency of light needed to remove an electron from chromium?

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Textbook Question

A minimum energy of 7.21⨉10-19 J is required to produce the photoelectric effect in chromium metal. (b) Light with a wavelength of 2.50⨉10-7 m falls on a piece of chromium in an evacuated glass tube. What is the minimum de Broglie wavelength of the emitted electrons? (Note that the energy of the incident light must be conserved; that is, the photon's energy must equal the sum of the energy needed to eject the electron plus the kinetic energy of the electron.)

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Textbook Question

An energetically excited hydrogen atom has its electron in a 5f subshell. The electron drops down to the 3d subshell, releasing a photon in the process. (b) What wavelength of light is emitted by the process?

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Textbook Question

An energetically excited hydrogen atom has its electron in a 5f subshell. The electron drops down to the 3d subshell, releasing a photon in the process. (c) The hydrogen atom now has a single electron in the 3d subshell. What is the energy in kJ/mol required to remove this electron?

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Textbook Question

Consider the noble gas xenon. (a) Write the electron configuration of xenon using the abbreviation of the previous noble gas.

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