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Ch.5 - Periodicity & Electronic Structure of Atoms
Chapter 5, Problem 126c

Imagine a universe in which the four quantum numbers can have the same possible values as in our universe except that the angular-momentum quantum number l can have integral values of 0, 1, 2...n + 1 (instead of 0, 1, 2..., n - 1). (c) Draw an orbital-filling diagram for the element with atomic number 12.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Quantum Numbers

Quantum numbers are sets of numerical values that describe the unique quantum state of an electron in an atom. There are four quantum numbers: the principal quantum number (n), which indicates the energy level; the angular momentum quantum number (l), which describes the shape of the orbital; the magnetic quantum number (m_l), which specifies the orientation of the orbital; and the spin quantum number (m_s), which indicates the direction of the electron's spin.
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Principal Quantum Number

Orbital Filling Order

The order in which electrons fill atomic orbitals is determined by the Aufbau principle, which states that electrons occupy the lowest energy orbitals first. The typical filling order follows the sequence dictated by the n + l rule, where orbitals are filled based on the sum of their principal and angular momentum quantum numbers. This order is crucial for constructing the electron configuration of an element.
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Molecular Orbital Diagram

Electron Configuration of Element 12

Element 12 is magnesium (Mg), which has an atomic number of 12, indicating it has 12 electrons. The electron configuration is determined by filling the orbitals according to the modified quantum number rules. In this case, with the angular momentum quantum number l allowed to take values up to n + 1, the electron configuration for magnesium would be 1s² 2s² 2p⁶ 3s², reflecting the distribution of its electrons across the available orbitals.
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Related Practice
Textbook Question
Why do the Earth and Sun have different emission spectra?
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Textbook Question
Orbital energies in single-electron atoms or ions, such as He+, can be described with an equation similar to the Balmer–Rydberg equation:

where Z is the atomic number. What wavelength of light in nanometers is emitted when the electron in He+ falls from n = 3 to n = 2?
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Textbook Question

Imagine a universe in which the four quantum numbers can have the same possible values as in our universe except that the angular-momentum quantum number l can have integral values of 0, 1, 2...n + 1 (instead of 0, 1, 2..., n - 1). (a) How many elements would be in the first two rows of the periodic table in this universe?

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Textbook Question
One watt (W) is equal to 1 J/s. Assuming that 5.0% of the energy output of a 75 W light bulb is visible light and that the average wavelength of the light is 550 nm, how many photons are emitted by the light bulb each second?
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Textbook Question
Microwave ovens work by irradiating food with microwave radiation, which is absorbed and converted into heat. Assum-ing that radiation with l = 15.0 cm is used, that all the energy is converted to heat, and that 4.184 J is needed to raise the temperature of 1.00 g of water by 1.00 °C, how many photons are necessary to raise the temperature of a 350 mL cup of water from 20 °C to 95 °C?
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Textbook Question
The amount of energy necessary to remove an electron from an atom is a quantity called the ionization energy, Ei. This energy can be measured by a technique called photoelectron spectroscopy, in which light of wavelength l is directed at an atom, causing an electron to be ejected. The kinetic energy of the ejected electron (Ek) is measured by determining its veloc-ity, v (Ek = mv2/2), and Ei is then calculated using the conservation of energy principle. That is, the energy of the incident light equals Ei plus Ek. What is the ionization energy of selenium atoms in kilojoules per mole if light with l = 48.2 nm produces electrons with a velocity of 2.371 * 106 m/s? The mass, m, of an electron is 9.109 * 10-31 kg.
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