Chapter 21, Problem 21.29
The oxalate ion is a bidentate ligand as indicated in Figure 21.8. Would you expect the carbonate ion to be a monodentate or bidentate ligand? Explain your reasoning.
Video transcript
Cobalt(III) trifluoroacetylacetonate, Co1tfac23, is a sixcoordinate, octahedral metal chelate in which three planar, bidentate tfac ligands are attached to a central Co atom:
(d) Draw a crystal field energy-level diagram for Co1tfac23, and predict its magnetic properties. (In this complex, tfac is a strong-field ligand.)
Based on effective nuclear charge (Zeff), which ion is the strongest oxidizing agent?
(a) Cu2+
(b) Ni2+
(c) Fe2+
(d) Mn2+
Look at the location in the periodic table of elements A, B, C, and D. What is the electron configuration of the transition metal in each of the following ions?
(a) A2+
(b) B+
Classify the following ligands as monodentate, bidentate, tri-dentate, or tetradentate. Which can form chelate rings?
(a)
(b)
(c)
(d)
Predict the number of unpaired electrons for each of the following.
(c) Zn2+
(d) Cr3+
Predict the number of unpaired electrons for each of the following.
(c) Mn3+
(d) Cr2+