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Ch.21 - Transition Elements and Coordination Chemistry

Chapter 21, Problem 21.2

Based on effective nuclear charge (Zeff), which ion is the strongest oxidizing agent? 

(a) Cu2+

(b) Ni2+

(c) Fe2+

(d) Mn2+

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Welcome everyone. Our next problem says, identify the ion with the highest oxidizing power. AC R three plus BC 03 plus CFE three plus and DT I three plus. So let's think about what would give an ion the highest oxidizing power. So this would mean that it has a great likelihood of oxidizing something and when something is oxidized, it loses electrons. So something with the highest oxidizing power would mean it has the greatest tendency to take electrons from another atom. So what we'd be looking at is the periodic trends of electron negativity because the more strong that attractive force on the electrons, the more likely your atom will be to attract electrons. So let's first think about where on the periodic table our atoms are and our answer choices and they are all in row four in the transition metal section. So I'm at a deep walk. So if I draw sort of rough two parallel lines, basically representing that D block and write them in order I have T I titanium as the farthest to the left, then chromium cr then iron fe and then the co which is cobalt. So let's think about our electron negativity train trend in the period table as we go from left to right electronegativity increases. That's because we're not adding any electrons into outer shells, not having any increased shielding from inner electrons. But the z effective Zeff in a subscript is increasing as you add more and more protons to the nucleus. So creating that greater attractive force, we also know that electron negativity will increase going up within the columns of the periodic table. But that's not relevant to this question because we're all in the same row. So let's put them in order and think about the ion, the highest oxidizing power most likely to take electrons, the most electron would be co cobalt as the farthest to the right in our grouping. So choice BC 03 plus is our ion with the highest oxidizing power. See you in the next video.
Related Practice
Textbook Question

Cobalt(III) trifluoroacetylacetonate, Co(tfac)3, is a sixc oordinate, octahedral metal chelate in which three planar, bidentate tfac ligands are attached to a central Co atom:

(a) Draw all possible diastereoisomers and enantiomers of Co(tfac)3.

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Textbook Question

Cobalt(III) trifluoroacetylacetonate, Co(tfac)3, is a sixcoordinate, octahedral metal chelate in which three planar, bidentate tfac ligands are attached to a central Co atom:

(b) Diastereoisomers A and B have dipole moments of 6.5 D and 3.8 D, respectively. Which of your diastereoisomers is A and which is B?

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Textbook Question

Cobalt(III) trifluoroacetylacetonate, Co1tfac23, is a sixcoordinate, octahedral metal chelate in which three planar, bidentate tfac ligands are attached to a central Co atom:

(d) Draw a crystal field energy-level diagram for Co1tfac23, and predict its magnetic properties. (In this complex, tfac is a strong-field ligand.)

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Textbook Question

Look at the location in the periodic table of elements A, B, C, and D. What is the electron configuration of the transition metal in each of the following ions?  

(a) A2+

(b) B+

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Textbook Question

The oxalate ion is a bidentate ligand as indicated in Figure 21.8. Would you expect the carbonate ion to be a monodentate or bidentate ligand? Explain your reasoning.

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Textbook Question

Classify the following ligands as monodentate, bidentate, tri-dentate, or tetradentate. Which can form chelate rings?

(a)  

(b) 

(c) 

(d) 

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