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Ch.17 - Applications of Aqueous Equilibria
Chapter 17, Problem 47

Is the pH greater than, equal to, or less than 7 after the neutralization of each of the following pairs of acids and bases? (c) HBr and aniline (C6H5NH2)

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Neutralization Reaction

A neutralization reaction occurs when an acid reacts with a base to produce water and a salt. In this process, the acidic properties of the acid and the basic properties of the base are neutralized, typically resulting in a solution that is closer to neutral pH, which is 7. The specific pH of the resulting solution depends on the strength of the acid and base involved.
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Strong vs. Weak Acids and Bases

Acids and bases can be classified as strong or weak based on their ability to dissociate in water. Strong acids, like HBr, completely dissociate into ions, while weak bases, like aniline, only partially dissociate. This distinction is crucial in predicting the pH of the solution after neutralization, as the strength of the acid and base will influence the final pH.
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pH Scale

The pH scale measures the acidity or basicity of a solution, ranging from 0 to 14. A pH of 7 is considered neutral, below 7 is acidic, and above 7 is basic. Understanding the pH scale is essential for determining the outcome of a neutralization reaction, as it helps to assess whether the resulting solution is acidic, neutral, or basic based on the properties of the reactants.
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Related Practice
Textbook Question

The following pictures represent solutions at various stages in the titration of sulfuric acid H2A (A2- = SO4 2-) with aqueous NaOH. (Na+ ions and water molecules have been omitted for clarity.)

. (a) To which of the following stages do solutions 1–4 correspond? (i) Halfway to the first equivalence point (ii) Halfway between the first and second equivalence points (iii) At the second equivalence point (iv) Beyond the second equivalence point

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Textbook Question

The following pictures represent solutions at various stages in the titration of sulfuric acid H2A (A2- = SO4 2-) with aqueous NaOH. (Na+ ions and water molecules have been omitted for clarity.)

. (b) Which solution has the highest pH? Draw a picture that represents the solution prior to addition of any NaOH.

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Textbook Question

The following pictures represent solutions of Ag2CrO4, which also may contain ions other than Ag+ and CrO42- that are not shown. Solution 1 is in equilibrium with solid Ag2CrO4. Will a precipitate of solid Ag2CrO4 form in solutions 2-4? Explain.

(1) (2) (3) (4)

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Textbook Question

Is the pH greater than, equal to, or less than 7 after the neutralization of each of the following pairs of acids and bases? (a) NaOH and benzoic acid (C6H5CO2H)

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Textbook Question

Is the pH greater than, equal to, or less than 7 after the neutralization of each of the following pairs of acids and bases? (c) KOH and HI

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Textbook Question
Which of the following mixtures has the higher pH? (a) Equal volumes of 0.10 M HCN and 0.10 M NaOH (b) Equal volumes of 0.10 M HClO4 and 0.10 M NaOH
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