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Ch.16 - Aqueous Equilibria: Acids & Bases
Chapter 16, Problem 45

Look at the electron-dot structures of the following molecules and ions: (b) Which can behave as a Lewis acid? Which can behave as a Lewis base?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Lewis Acids and Bases

Lewis acids are substances that can accept an electron pair, while Lewis bases are those that can donate an electron pair. This definition expands the concept of acids and bases beyond protons, focusing instead on electron pair interactions. Understanding this distinction is crucial for identifying the behavior of molecules and ions in chemical reactions.
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Electron-Dot Structures

Electron-dot structures, or Lewis structures, visually represent the valence electrons of atoms within a molecule or ion. They help in predicting how atoms bond and interact with each other, as well as in identifying lone pairs and formal charges. Analyzing these structures is essential for determining which species can act as Lewis acids or bases.
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Molecular Geometry and Hybridization

The geometry and hybridization of a molecule influence its reactivity and ability to act as a Lewis acid or base. For instance, molecules with empty orbitals can accept electron pairs, making them Lewis acids, while those with lone pairs can donate electrons, acting as Lewis bases. Understanding these spatial arrangements is key to predicting chemical behavior.
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