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Ch.16 - Aqueous Equilibria: Acids & Bases
Chapter 16, Problem 60a

Arrange each group of compounds in order of increasing acid strength. Explain your reasoning. (a) HCl, H2S, PH3

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Acid Strength

Acid strength refers to the ability of an acid to donate protons (H+) in a solution. Stronger acids dissociate more completely in water, resulting in a higher concentration of H+ ions. The strength of an acid is influenced by factors such as bond strength, electronegativity of the atoms involved, and the stability of the conjugate base formed after deprotonation.
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Electronegativity

Electronegativity is the tendency of an atom to attract electrons in a chemical bond. In the context of acids, higher electronegativity of the central atom typically leads to stronger acids, as it stabilizes the negative charge on the conjugate base after the acid donates a proton. For example, in the series HCl, H2S, and PH3, the electronegativity of chlorine is greater than that of sulfur and phosphorus, contributing to HCl's stronger acidic nature.
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Conjugate Base Stability

The stability of the conjugate base formed after an acid donates a proton is crucial in determining acid strength. A more stable conjugate base corresponds to a stronger acid, as the equilibrium favors the formation of the products. Factors affecting conjugate base stability include resonance, electronegativity, and the size of the atom bearing the negative charge. In the given compounds, the stability of the conjugate bases influences the order of acid strength.
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