Chapter 14, Problem 42
Consider the first-order reaction AS B in which A molecules (red spheres) are converted to B molecules (blue spheres).
(a) Given the pictures at t = 0 min and t = 1 min, draw pictures that show the number of A and B molecules present at t = 2 min and t = 3 min.Video transcript
The following reaction is first order in A (red spheres) and first order in B (blue spheres): A + B → Products Rate = k[A][B]
(b) What are the relative values of the rate constant k for vessels (1)–(4)?
Consider the first-order decomposition of A molecules (red spheres) in three vessels of equal volume. (1)-(3)
(b) What are the relative half-lives of the reactions in vessels (1)–(3)?
The following pictures represent the progress of the reaction AS B in which A molecules (red spheres) are converted to B molecules (blue spheres).
(b) Draw a picture that shows the number of A and B molecules present at t = 3 min.
The following pictures represent the progress of the reaction AS B in which A molecules (red spheres) are converted to B molecules (blue spheres).
(c) Suppose that each sphere represents 6.0⨉1021 molecules and that the volume of the container is 1.0 L. What is the rate constant for the reaction in the usual units?