Ch.14 - Chemical Kinetics
Chapter 14, Problem 39
(b) Write the balanced reaction that corresponds to the data in the graph.
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Related Practice
Textbook Question
A key reaction in the upper atmosphere is
O31g2 + O1g2 ¡ 2 O21g2
For this process, the energy of activation for the forward
reaction, Ea1fwd2, is 19 kJ/mol, and the enthalpy change for
the reaction, ΔHrxn, is -392 kJ>mol. What is the energy of
activation for the reverse reaction, Ea1reverse2? (LO 14.10)
(a) 411 kJ/mol (b) 392 kJ/mol
(c) 373 kJ/mol (d) 196 kJ/mol
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Textbook Question
To answer questions 13–15, refer to the mechanism:
H2O21aq2 + I-1aq2¡OH-1aq2 + HOI1aq2
Slower, rate-determining
HOI1aq2 + I-1aq2¡OH-1aq2 + I21aq2 Faster
2 OH-1aq2 + 2 H3O+1aq2¡4 H2O1l2 Faster
Identify the catalyst and intermediate(s) in the mechanism.
(LO 14.12, 14.16)
(a) Catalyst = I-, intermediates = OH-, HOI
(b) Catalyst = H3O+, intermediate = HOI
(c) No catalyst, intermediate = I2
(d) No catalyst, intermediates = OH-, HOI
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Textbook Question
Ammonia is manufactured in large amounts by the reaction
N2(g) + 3 H2(g) → 2 NH3(g)
(a) How is the rate of consumption of H2 related to the rate of consumption of N2?
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Textbook Question
The following reaction is first order in A (red spheres) and first order in B (blue spheres): A + B → Products Rate = k[A][B]
(a) What are the relative rates of this reaction in vessels (1)–(4)? Each vessel has the same volume.
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Textbook Question
The following reaction is first order in A (red spheres) and first order in B (blue spheres): A + B → Products Rate = k[A][B]
(b) What are the relative values of the rate constant k for vessels (1)–(4)?
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Textbook Question
Consider the first-order decomposition of A molecules (red
spheres) in three vessels of equal volume.
(1)-(3)
(c) How will the rates and half-lives be affected if the
volume
of each vessel is decreased by a factor of 2?
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