Ch.14 - Chemical Kinetics
Chapter 14, Problem 13
To answer questions 13–15, refer to the mechanism: H2O21aq2 + I-1aq2¡OH-1aq2 + HOI1aq2 Slower, rate-determining HOI1aq2 + I-1aq2¡OH-1aq2 + I21aq2 Faster 2 OH-1aq2 + 2 H3O+1aq2¡4 H2O1l2 Faster Identify the catalyst and intermediate(s) in the mechanism. (LO 14.12, 14.16) (a) Catalyst = I-, intermediates = OH-, HOI (b) Catalyst = H3O+, intermediate = HOI (c) No catalyst, intermediate = I2 (d) No catalyst, intermediates = OH-, HOI
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Related Practice
Textbook Question
The gas phase decomposition of HI has the following rate law:
2 HI1g2¡H21g2 + I21g2 Rate = k3HI42
At 443 °C, k = 30.1 M-1 min-1. If the initial concentration
of HI is 0.010 M, what is the concentration after 1.5 hours?
(LO 14.8)
(a) 6.9 * 10-3 M (b) 1.8 * 10-3 M
(c) 3.6 * 10-4 M (d) 8.9 * 10-4 M
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Textbook Question
Chlorine monoxide (ClO) decomposes at room temperature
according to the reaction
2 ClO1g2¡Cl21g2 + O21g2
The concentration of ClO was monitored over time, and
three graphs were made:
What is the rate law for the reaction? (LO 14.9)
(a) Rate = k (b) Rate = k3ClO4
(c) Rate = k3ClO42 (d) Rate = k3ClO43
M14_MCMU6230_
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Textbook Question
A key reaction in the upper atmosphere is
O31g2 + O1g2 ¡ 2 O21g2
For this process, the energy of activation for the forward
reaction, Ea1fwd2, is 19 kJ/mol, and the enthalpy change for
the reaction, ΔHrxn, is -392 kJ>mol. What is the energy of
activation for the reverse reaction, Ea1reverse2? (LO 14.10)
(a) 411 kJ/mol (b) 392 kJ/mol
(c) 373 kJ/mol (d) 196 kJ/mol
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Textbook Question
Ammonia is manufactured in large amounts by the reaction
N2(g) + 3 H2(g) → 2 NH3(g)
(a) How is the rate of consumption of H2 related to the rate of consumption of N2?
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Textbook Question
(b) Write the balanced reaction that corresponds to the data
in the graph.
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Textbook Question
The following reaction is first order in A (red spheres) and first order in B (blue spheres): A + B → Products Rate = k[A][B]
(a) What are the relative rates of this reaction in vessels (1)–(4)? Each vessel has the same volume.
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