Ch.13 - Solutions & Their Properties
Chapter 13, Problem 39
Which would you expect to have the larger hydration energy, SO42- or ClO4-? Explain.
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Textbook Question
The following phase diagram shows part of the liquid–vapor phase-transition boundaries for pure ether and a solution of a nonvolatile solute in ether.
(b) What is the approximate mo#lal concentration of the sol-ute? [Kb for ether is 2.021°C kg2>mol.]
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Textbook Question
Two beakers, one with pure water (blue) and the other with a solution of NaCl in water (green), are placed in a closed container as represented by drawing (a). Which of the draw- ings (b)–(d) represents what the beakers will look like after a substantial amount of time has passed?
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Textbook Question
If a single 5-g block of NaCl is placed in water, it dissolves slowly, but if 5 g of powdered NaCl is placed in water, it dis- solves rapidly. Explain.
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Textbook Question
Classify the strongest type of intermolecular force in the follow- ing interactions: solvent–solvent, solvent–solute, and solute– solute when solid iodine 1I22 is placed in the water. Based on these interactions, predict whether I2 is soluble in water.
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Textbook Question
The following pictures represent solutions of AgCl, which also may contain ions other than Ag+ and Cl- that are not shown. If solution 1 is a saturated solution of AgCl, classify solutions 2–4 as unsaturated, saturated, or supersaturated.
(1)
(2)
(3)
(4)
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Textbook Question
Predict whether the solubility of butane, C4H10, is greater in water or benzene, C6H6.
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