Ch.13 - Solutions & Their Properties
Chapter 13, Problem 33
Two beakers, one with pure water (blue) and the other with a solution of NaCl in water (green), are placed in a closed container as represented by drawing (a). Which of the draw- ings (b)–(d) represents what the beakers will look like after a substantial amount of time has passed?
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Textbook Question
Hemoglobin is a large molecule that carries oxygen in the body. An aqueous solution that contains 2.61 g of hemoglo- bin in 100.0 mL has an osmotic pressure of 7.52 mmHg at 25 °C. What is the molar mass of the hemoglobin? Assume hemoglobin does not dissociate in water. (LO 13.15)
(a) 1.96 * 103 g>mol (b) 84.8 g/mol
(c) 6.45 * 104 g>mol (d) 3.65 * 103 g>mol
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Textbook Question
The following phase diagram shows part of the vapor- pressure curves for a pure liquid (green curve) and a solution of the first liquid with a second volatile liquid (red curve). (a) Is the boiling point of the second liquid higher or lower than that of the first liquid?
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Textbook Question
The following phase diagram shows part of the liquid–vapor phase-transition boundaries for pure ether and a solution of a nonvolatile solute in ether.
(b) What is the approximate mo#lal concentration of the sol-ute? [Kb for ether is 2.021°C kg2>mol.]
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Textbook Question
If a single 5-g block of NaCl is placed in water, it dissolves slowly, but if 5 g of powdered NaCl is placed in water, it dis- solves rapidly. Explain.
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Textbook Question
Which would you expect to have the larger hydration
energy, SO42- or ClO4-? Explain.
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Textbook Question
Classify the strongest type of intermolecular force in the follow- ing interactions: solvent–solvent, solvent–solute, and solute– solute when solid iodine 1I22 is placed in the water. Based on these interactions, predict whether I2 is soluble in water.
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