Ch.13 - Solutions & Their Properties
Chapter 13, Problem 15
Hemoglobin is a large molecule that carries oxygen in the body. An aqueous solution that contains 2.61 g of hemoglo- bin in 100.0 mL has an osmotic pressure of 7.52 mmHg at 25 °C. What is the molar mass of the hemoglobin? Assume hemoglobin does not dissociate in water. (LO 13.15) (a) 1.96 * 103 g>mol (b) 84.8 g/mol (c) 6.45 * 104 g>mol (d) 3.65 * 103 g>mol
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Related Practice
Textbook Question
Which of the following solutions has the lowest vapor pres- sure? (Assume complete dissociation for ionic compounds.) (LO 13.10)
(a) An aqueous solution of 0.25 m Ca1NO322
(b) An aqueous solution of 0.30 m sodium chloride (NaCl)
(c) A mixture of 50 mL of water and 50 mL of ethanol
1CH3CH2OH2
(d) A mixture of 25 mL of water and 50 mL of ethanol
1CH3CH2OH2
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Textbook Question
12. A solution contains 4.08 g of chloroform 1CHCl32 and
9.29 g of acetone 1CH3COCH32. The vapor pressures at 35
°C of pure chloroform and pure acetone are 295 torr and 332 torr, respectively. Assuming ideal behavior, calculate the vapor pressure above the solution. (LO 13.12)
(a) 256 torr (b) 314 torr
(c) 325 torr (d) 462 torr
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Textbook Question
How many kilograms of ethylene glycol (automobile anti- freeze, C2H6O2) dissolved in 3.55 kg of water are needed to lower the freezing point of water in an automobile radiator
to - 22.0 °C? The molal freezing point depression constant for water is Kf = 1.86 1°C kg2>mol. (LO 13.13)
(a) 0.865 kg (b) 0.0420 kg
(c) 9.01 kg (d) 2.61 kg
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Textbook Question
The following phase diagram shows part of the vapor- pressure curves for a pure liquid (green curve) and a solution of the first liquid with a second volatile liquid (red curve). (a) Is the boiling point of the second liquid higher or lower than that of the first liquid?
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Textbook Question
The following phase diagram shows part of the liquid–vapor phase-transition boundaries for pure ether and a solution of a nonvolatile solute in ether.
(b) What is the approximate mo#lal concentration of the sol-ute? [Kb for ether is 2.021°C kg2>mol.]
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Textbook Question
Two beakers, one with pure water (blue) and the other with a solution of NaCl in water (green), are placed in a closed container as represented by drawing (a). Which of the draw- ings (b)–(d) represents what the beakers will look like after a substantial amount of time has passed?
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