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Ch.12 - Solids and Solid-State Materials
Chapter 12, Problem 54

Silicon carbide, SiC, is a covalent network solid with a structure similar to that of diamond. Sketch a small portion of the SiC structure.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Covalent Network Solids

Covalent network solids are materials where atoms are bonded together by a network of covalent bonds, forming a continuous structure. This results in high melting points, hardness, and electrical non-conductivity. Silicon carbide (SiC) exemplifies this type of solid, as its atoms are arranged in a three-dimensional lattice similar to that of diamond, contributing to its exceptional strength and thermal stability.
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Crystal Structure

The crystal structure of a material refers to the orderly arrangement of atoms within the solid. In the case of silicon carbide, the structure can be visualized as a repeating pattern of silicon and carbon atoms, forming tetrahedral units. Understanding the crystal structure is essential for predicting the material's properties, such as its hardness and thermal conductivity.
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Tetrahedral Coordination

Tetrahedral coordination is a geometric arrangement where a central atom is surrounded by four other atoms at the corners of a tetrahedron. In SiC, silicon atoms are tetrahedrally coordinated with carbon atoms, leading to a strong and stable structure. This coordination is crucial for the material's mechanical properties and contributes to its high resistance to thermal and chemical degradation.
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