Ch.11 - Liquids & Phase Changes
Chapter 11, Problem 72
Two compounds (labeled I and II) have a liquid crystal state. Predict which compound has a higher temperature associ- ated with the solid to liquid crystal phase change. Explain your reasoning.
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Water at room temperature is placed in a flask connected by rubber tubing to a vacuum pump, and the pump is turned on. After several minutes, the volume of the water has decreased, and what remains has turned to ice. Explain
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Textbook Question
Benzene has a melting point of 5.53 °C and a boiling point of 80.09 °C at atmospheric pressure. Its density is0.8787 g>cm3 when liquid and 0.899 g>cm3 when solid; it has Tc = 289.01 °C, Pc = 48.34 atm, Tt = 5.52 °C, and Pt = 0.0473 atm. Starting from a point at 200 K and
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(4) Finally, decrease P to 0.0025 atm while keeping T
constant.
What is your starting phase, and what is your final phase?
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Textbook Question
Intermolecular forces are important in creating ordered arrangements in liquid crystals. What types of intermolecu- lar forces exist in a sample of the following compound?
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Textbook Question
The compound cholesteryl benzoate is a rod-like molecule that undergoes a phase change from the solid to the liq- uid crystal phase at 145.5 °C. When cholesteryl benzoate is mixed with cholesteryl oleyl carbonate, a molecule with a curved shape, the temperature of the solid to liquid crys- tal transition changes. Predict if the transition temperature increases or decreases and explain your reasoning.
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Textbook Question
The chlorofluorocarbon refrigerant trichlorofluoromethane, CCl3F, has Pvap = 100.0 mm Hg at -23 °C and ΔHvap
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Textbook Question
Substance X has a vapor pressure of 100 mm Hg at its triple point (48 °C). When 1 mol of X is heated at 1 atm pres- sure with a constant rate of heat input, the following heating curve is obtained:
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