Skip to main content
Ch.11 - Liquids & Phase Changes

Chapter 11, Problem 70

Intermolecular forces are important in creating ordered arrangements in liquid crystals. What types of intermolecu- lar forces exist in a sample of the following compound?

Verified Solution
Video duration:
1m
This video solution was recommended by our tutors as helpful for the problem above.
410
views
Was this helpful?

Video transcript

Hey everyone, we're told that the formation of ordered structures in liquid crystals is dependent on inter molecular interactions. What inter molecular forces are present in the following sample. First. Starting off with hydrogen bonding, we do see that this is actually present. We know this is present because hydrogen bonding occurs in compounds where hydrogen is directly connected to an electro negative element, which would be our fawn elements, flooring oxygen and nitrogen. As we can see in our sample, we have a nitrogen attached to a hydrogen. So we do have hydrogen bonding present. Now let's go ahead and look at dipole dipole interaction, Dipole dipole interaction occurs between two polar covalin compounds. So we do see that this is actually present as well. And the reason why is because the electro negativity difference between carbon and oxygen is 1.0, so our carbon oxygen bond is polar. So that means this sample exhibits dipole dipole interaction. Now let's go ahead and look at dispersion forces. Dispersion forces is present as well. And the reason why is because this is present in all compounds. Next looking at ion dipole interaction, Ion dipole interaction occurs between an ion and a polar covalin compound. Looking at our sample, we do not see any ions present. So this can't be our answer. Next looking at induced dipole interaction, this occurs when a non polar compound interacts with a polar compound. Again, we do not see this present as well. So this can't be our answer. Now looking at our answer choices, it looks like answer choice B matches our answer. Now, I hope that made sense and let us know if you have any questions.
Related Practice
Textbook Question
When ethyl alcohol, CH3CH2OH, dissolves in water, how many hydrogen bonds are formed between one ethyl alcohol molecule and surrounding water molecules? Sketch the hydro- gen bonding interactions. (Hint: Add lone pairs of electrons to the structure before drawing hydrogen bonds.)
1148
views
Textbook Question
Water at room temperature is placed in a flask connected by rubber tubing to a vacuum pump, and the pump is turned on. After several minutes, the volume of the water has decreased, and what remains has turned to ice. Explain
366
views
Textbook Question
Benzene has a melting point of 5.53 °C and a boiling point of 80.09 °C at atmospheric pressure. Its density is0.8787 g>cm3 when liquid and 0.899 g>cm3 when solid; it has Tc = 289.01 °C, Pc = 48.34 atm, Tt = 5.52 °C, and Pt = 0.0473 atm. Starting from a point at 200 K and 66.5 atm, trace the following path on a phase diagram. (1) First, increase T to 585 K while keeping P constant. (2) Next, decrease P to 38.5 atm while keeping T constant. (3) Then, decrease T to 278.66 K while keeping P constant. (4) Finally, decrease P to 0.0025 atm while keeping T constant. What is your starting phase, and what is your final phase?
2486
views
Textbook Question

Two compounds (labeled I and II) have a liquid crystal state. Predict which compound has a higher temperature associ- ated with the solid to liquid crystal phase change. Explain your reasoning.

339
views
Textbook Question
The compound cholesteryl benzoate is a rod-like molecule that undergoes a phase change from the solid to the liq- uid crystal phase at 145.5 °C. When cholesteryl benzoate is mixed with cholesteryl oleyl carbonate, a molecule with a curved shape, the temperature of the solid to liquid crys- tal transition changes. Predict if the transition temperature increases or decreases and explain your reasoning.
754
views
Textbook Question
The chlorofluorocarbon refrigerant trichlorofluoromethane, CCl3F, has Pvap = 100.0 mm Hg at -23 °C and ΔHvap = 24.77 kJ>mol. (b) What is ΔSvap for trichlorofluoromethane?
776
views