Ch.11 - Liquids & Phase Changes
Chapter 11, Problem 73
The compound cholesteryl benzoate is a rod-like molecule that undergoes a phase change from the solid to the liq- uid crystal phase at 145.5 °C. When cholesteryl benzoate is mixed with cholesteryl oleyl carbonate, a molecule with a curved shape, the temperature of the solid to liquid crys- tal transition changes. Predict if the transition temperature increases or decreases and explain your reasoning.
Verified Solution
Video duration:
1mThis video solution was recommended by our tutors as helpful for the problem above.
754
views
Was this helpful?
Video transcript
Related Practice
Textbook Question
Benzene has a melting point of 5.53 °C and a boiling point of 80.09 °C at atmospheric pressure. Its density is0.8787 g>cm3 when liquid and 0.899 g>cm3 when solid; it has Tc = 289.01 °C, Pc = 48.34 atm, Tt = 5.52 °C, and Pt = 0.0473 atm. Starting from a point at 200 K and
66.5 atm, trace the following path on a phase diagram. (1) First, increase T to 585 K while keeping P constant.
(2) Next, decrease P to 38.5 atm while keeping T constant.
(3) Then, decrease T to 278.66 K while keeping P constant.
(4) Finally, decrease P to 0.0025 atm while keeping T
constant.
What is your starting phase, and what is your final phase?
2486
views
Textbook Question
Intermolecular forces are important in creating ordered arrangements in liquid crystals. What types of intermolecu- lar forces exist in a sample of the following compound?
410
views
Textbook Question
Two compounds (labeled I and II) have a liquid crystal state. Predict which compound has a higher temperature associ- ated with the solid to liquid crystal phase change. Explain your reasoning.
339
views
Textbook Question
The chlorofluorocarbon refrigerant trichlorofluoromethane, CCl3F, has Pvap = 100.0 mm Hg at -23 °C and ΔHvap
= 24.77 kJ>mol.
(b) What is ΔSvap for trichlorofluoromethane?
776
views
Textbook Question
Substance X has a vapor pressure of 100 mm Hg at its triple point (48 °C). When 1 mol of X is heated at 1 atm pres- sure with a constant rate of heat input, the following heating curve is obtained:
(b) For each of the following, choose which phase of X (solid, liquid, or gas) fits the description.
(iii) Has the greatest specific heat
511
views
Textbook Question
Which of the following substances would you expect to have
a nonzero dipole moment? Explain, and show the direction
of each.
(a) Cl2O
(b) XeF4
(c) Chloroethane, CH3CH2Cl
(d) BF3
858
views