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Ch.10 - Gases: Their Properties & Behavior
Chapter 10, Problem 5

Propane gas 1C3H82 is often used as fuel in rural areas. How many liters of CO2 are formed at STP by the complete combustion of the propane in a container with a volume of 15.0 L and a pressure of 4.50 atm at 25.0 °C? The equation for the combustion of propane is: C3H81g2 + 5 O21g2¡3 CO21g2 + 4 H2O1l2 (LO 10.4, 10.5) (a) 61.8 L (b) 186 L (c) 20.6 L (d) 2.21 * 103 L

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Stoichiometry of Combustion Reactions

Stoichiometry involves using balanced chemical equations to determine the relationships between reactants and products. In the combustion of propane (C3H8), the balanced equation shows that one mole of propane reacts with five moles of oxygen to produce three moles of carbon dioxide and four moles of water. Understanding this ratio is essential for calculating the amount of CO2 produced from a given amount of propane.
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Ideal Gas Law

The Ideal Gas Law (PV = nRT) relates the pressure, volume, temperature, and number of moles of a gas. At standard temperature and pressure (STP), one mole of an ideal gas occupies 22.4 liters. This law is crucial for converting the number of moles of CO2 produced from the combustion reaction into a volume at STP, allowing for the determination of how many liters of CO2 are formed.
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Conditions of STP

Standard Temperature and Pressure (STP) is defined as a temperature of 0 °C (273.15 K) and a pressure of 1 atm. Under these conditions, the behavior of gases can be predicted more accurately. When calculating the volume of gases produced in reactions, it is important to convert the conditions of the reaction (in this case, 25 °C and 4.50 atm) to STP to ensure accurate results.
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Related Practice
Textbook Question
What is the pressure of the gas inside the bulb (atm) if the outside pressure is 0.92 atm? (a) 1.1 atm (b) 2.6 atm (c) 0.22 atm (d) 0.70 atm
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Textbook Question
Assume that you have a gas cylinder with a movable piston filled with oxygen. The initial conditions are T = 250 K, n = 0.140 mol O2, and P = 1.00 atm. If the initial volume is 1.0 L, what is the volume when the temperature is increased to 400 K and the pressure is decreased to 0.75 atm? (LO 10.3) (a) 2.1 L (b) 1.2 L (c) 0.83 L (d) 1.6 L
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Many laboratory gases are sold in steel cylinders with a volume of 43.8 L. What is the mass in grams of argon inside a cylinder whose pressure is 17,180 kPa at 20 °C? (LO 10.4) (a) 1.83 * 107 g (b) 1.81 * 105 g (c) 1.23 * 104 g (d) 122 g
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Textbook Question
Trimix is a gas mixture consisting of oxygen, helium, and nitrogen used for deep scuba dives. The helium is included to reduce the effects of nitrogen narcosis and oxygen toxicity that occur when too much nitrogen and oxygen dissolve in the blood. A tank of Trimix has a total pressure of 200 atm, and the partial pressure of He is 34 atm. What is the percent by volume of He in the tank? (LO 10.7) (a) 17% (b) 38% (c) 23% (d) 83%
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Textbook Question
The apparatus shown consists of three bulbs connected by stopcocks. What is the pressure inside the system when the stopcocks are opened? Assume that the lines connecting the bulbs have zero volume and that the temperature remains constant. (LO 10.3, 10.7) (a) 1.10 atm (b) 1.73 atm (c) 4.14 atm (d) 1.41 atm

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Textbook Question
A mixture of chlorine, hydrogen, and oxygen gas is in a container at STP. Which curve represents oxygen gas? (LO 10.8) (a) Curve (a) (b) Curve (b) (c) Curve (c)

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