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Ch.20 - Nuclear Chemistry
Chapter 20, Problem 104

One of the new superheavy elements added to the periodic table in 2016 was synthesized when a beam of 48Ca ions was directed at a target of 249Cf. (a) Write a balanced nuclear equation for the formation of this element. (b) What isotope is formed after the nuclide formed in the nuclear transmutation reaction in part (a) emits four alpha particles?

Verified step by step guidance
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Step 1: Identify the reactants and products in the nuclear reaction. The reactants are 48Ca (Calcium-48) and 249Cf (Californium-249). The product is a new superheavy element, which we can denote as element X with a mass number A and atomic number Z.
Step 2: Write the nuclear equation for the synthesis of the new element. The equation is: \[ ^{48}_{20}\text{Ca} + ^{249}_{98}\text{Cf} \rightarrow ^{A}_{Z}\text{X} + ^{1}_{0}\text{n} \] where a neutron is also produced.
Step 3: Balance the nuclear equation by ensuring the sum of atomic numbers and mass numbers on both sides are equal. Calculate A and Z for the new element X using the conservation of mass and atomic numbers.
Step 4: Determine the isotope formed after the emission of four alpha particles. An alpha particle is \( ^{4}_{2}\text{He} \), so emitting four alpha particles will decrease the mass number by 16 and the atomic number by 8.
Step 5: Write the nuclear equation for the decay of the new element by emitting four alpha particles. The equation is: \[ ^{A}_{Z}\text{X} \rightarrow ^{(A-16)}_{(Z-8)}\text{Y} + 4(^{4}_{2}\text{He}) \] where Y is the resulting isotope.
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Element was prepared in 1982 by bombardment of atoms with atoms. Identify the other product that must have formed, and write a balanced nuclear equation assuming no other products were formed.
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Molybdenum-99 is formed by neutron bombardment of a naturally occurring isotope of Mo. If one neutron is absorbed and no by-products are formed, what is the starting isotope?
Textbook Question
One of the new superheavy elements added to the periodic table in 2016 was synthesized when a beam of 48Ca ions was directed at a target of 243Am. (a) Write a balanced nuclear equation for the formation of this element. (b) What isotope is formed after the nuclide formed in the nuclear transmutation reaction in part (a) emits one alpha particle? (c) How many alpha particles were emitted to reach the isotope 268Db, the final decay product?
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Textbook Question
Fraud in science is rare but does happen occasionally. In 1999, the creation of three superheavy elements (one new) was claimed when 208Pb was bombarded with 86Kr. The claim was subsequently found to be fraudulent and was with-drawn. Identify the isotopes X, Y, and Z that were claimed.
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Textbook Question
The most abundant isotope of uranium, 238U, does not undergo fission. In a breeder reactor, however, a 238U atom captures a neutron and emits two b particles to make a fis-sionable isotope of plutonium, which can then be used as fuel in a nuclear reactor. Write a balanced nuclear equation.
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