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Ch.15 - Chemical Equilibrium

Chapter 15, Problem 4d

The following diagram represents a reaction shown going to completion. Each molecule in the diagram represents 0.1 mol, and the volume of the box is 1.0 L. (d) Assuming that all of the molecules are in the gas phase, calculate n, the change in the number of gas molecules that accompanies the reaction. [Section 15.2]

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Hello everyone today. We have the following problem. Consider the following diagram of a gas phase reaction. Whereas each molecule represents one mole in a box with a volume of one leader. What does it change the number of gas molecules as a result of the reaction? So we have a box on the left here in the box on the right for the first box we see that we have five molecules of X Gas. We have seven molecules of Why gas. In the second box we have four molecules of XY two gas and we also have one excess of x gas and one excess of gas. So this tells us that our reaction is going to be four X gas molecules reacted with six y gas molecules to form four X molecules As well as why three molecules. and so simplified simply dividing this entire both sides by two. We get two x molecules plus three y molecules to give us two x molecules as well as to why wallet kills. And so our change in N is going to essentially be products minus our reactions. And so our products, we have two moles And for our reactant we have five moles. And so our change and N is going to be negative three. Giving us our final answer. I hope this helped. And until next time
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Textbook Question

(a) Based on the following energy profile, predict whether kf > kr or kf < kr. [Section 15.1]

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Textbook Question

The following diagrams represent a hypothetical reaction A Β‘ B, with A represented by red spheres and B represented by blue spheres. The sequence from left to right represents the system as time passes. Does the system reach equilibrium? If so, in which diagram(s) is the system in equilibrium? [Sections 15.1 and 15.2]

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Textbook Question

Ethene (C2H4) reacts with halogens (X2) by the following reaction:

C2H4(𝑔) + X2(𝑔) β‡Œ C2H4X2(𝑔)

The following figures represent the concentrations at equilibrium at the same temperature when X2 is Cl2 (green), Br2 (brown), and I2 (purple). List the equilibria from smallest to largest equilibrium constant. [Section 15.3]

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Textbook Question

When lead(IV) oxide is heated above 300Β°C, it decomposes according to the reaction, 2 PbO2(𝑠) β‡Œ 2PbO(𝑠) + O2(𝑔). Consider the two sealed vessels of PbO2 shown here. If both vessels are heated to 400Β°C and allowed to come to equilibrium, which of the following statements is or are true? a. There will be less PbO2 remaining in vessel A than in vessel B.

Textbook Question

When lead(IV) oxide is heated above 300Β°C, it decomposes according to the reaction, 2 PbO2(𝑠)β‡Œ2PbO(𝑠)+O2(𝑔). Consider the two sealed vessels of PbO2 shown here. If both vessels are heated to 400Β°C and allowed to come to equilibrium, which of the following statements is or are true?

b. The solid left at the bottom of each vessel will be a mixture of PbO2(𝑠) and PbO(𝑠).