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Ch.18 - Chemistry of the Environment
Chapter 18, Problem 78a

The estimated average concentration of NO2 in air in the United States in 2006 was 0.016 ppm. (a) Calculate the partial pressure of the NO2 in a sample of this air when the atmospheric pressure is 755 torr (99.1 kPa).

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Partial Pressure

Partial pressure refers to the pressure exerted by a single component of a gas mixture. It can be calculated using Dalton's Law, which states that the total pressure of a gas mixture is equal to the sum of the partial pressures of its individual gases. In this context, the partial pressure of NO2 can be determined by multiplying its concentration (in ppm) by the total atmospheric pressure.
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Concentration Units

Concentration can be expressed in various units, including parts per million (ppm), which indicates the number of parts of a substance in one million parts of the total solution or mixture. To convert ppm to a more usable form for calculations, it is often necessary to relate it to the total pressure of the gas mixture, allowing for the determination of the partial pressure of the specific gas.
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Gas Laws

Gas laws describe the behavior of gases under various conditions of temperature, volume, and pressure. The ideal gas law (PV=nRT) is particularly relevant, as it relates pressure (P), volume (V), and temperature (T) to the number of moles (n) of gas. Understanding these laws is essential for calculating the behavior of gases in different scenarios, including determining partial pressures from concentrations.
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Related Practice
Textbook Question

Write balanced chemical equations for each of the following reactions: (d) Nitrogen dioxide dissolves in water to form nitric acid and nitric oxide.

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Textbook Question

(b) Will Mg(OH)2 precipitate when 4.0 g of Na2CO3 is added to 1.00 L of a solution containing 125 ppm of Mg2+?

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Textbook Question

(b) Concentrations of lead in the bloodstream are often quoted in units of μg/dL. Averaged over the entire country, the mean concentration of lead in the blood was measured to be 1.6 μg/dL in 2008. Express this concentration in ppb.

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Textbook Question

In 1986 an electrical power plant in Taylorsville, Georgia, burned 8,376,726 tons of coal, a national record at that time. (a) Assuming that the coal was 83% carbon and 2.5% sulfur and that combustion was complete, calculate the number of tons of carbon dioxide and sulfur dioxide pro- duced by the plant during the year.

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Textbook Question

The water supply for a midwestern city contains the following impurities: coarse sand, finely divided particulates, nitrate ions, trihalomethanes, dissolved phosphorus in the form of phosphates, potentially harmful bacterial strains, dissolved organic substances. Which of the following processes or agents, if any, is effective in removing each of these impurities: coarse sand filtration, activated carbon filtration, aeration, ozonization, precipitation with aluminum hydroxide?

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Textbook Question

An impurity in water has an extinction coefficient of 3.45⨉103 M-1 cm-1 at 280 nm, its absorption maximum (A Closer Look, p. 576). Below 50 ppb, the impurity is not a problem for human health. Given that most spectrometers cannot detect absorbances less than 0.0001 with good reliability, is measuring the absorbance of a water sample at 280 nm a good way to detect concentrations of the impurity above the 50-ppb threshold?

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