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Ch.18 - Chemistry of the Environment
Chapter 18, Problem 11a

(a) What is the primary basis for the division of the atmosphere into different regions?

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Identify the primary factor that influences the division of the atmosphere into different regions.
Consider how temperature changes with altitude in the atmosphere.
Recognize that the atmosphere is divided into layers based on temperature gradients.
Understand that each atmospheric layer has distinct temperature characteristics.
Conclude that the primary basis for the division of the atmosphere into different regions is the variation in temperature with altitude.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Atmospheric Layers

The atmosphere is divided into distinct layers based on temperature gradients and composition. The primary layers include the troposphere, stratosphere, mesosphere, thermosphere, and exosphere. Each layer has unique characteristics, such as temperature changes with altitude and the presence of specific gases, which influence weather patterns and climate.
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Temperature Gradient

The temperature gradient refers to the change in temperature with altitude in the atmosphere. In the troposphere, temperature decreases with height, while in the stratosphere, it increases due to the absorption of ultraviolet radiation by ozone. This gradient is crucial for understanding atmospheric stability and the behavior of weather systems.
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Composition of the Atmosphere

The composition of the atmosphere varies with altitude, affecting its physical and chemical properties. The lower atmosphere contains a higher concentration of water vapor and pollutants, while the upper layers have less density and different gas compositions. This variation plays a significant role in atmospheric dynamics and the formation of different weather phenomena.
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Related Practice
Textbook Question

Where does the energy come from to evaporate the esti- mated 425,000 km3 of water that annually leaves the oceans, as illustrated here? [Section 18.3]

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Open Question
In the following instances, which choice is greener in a chemical process and why? (b) A reagent for the reaction that can be obtained from corn husks or one that is obtained from petroleum. (c) A process that produces no by-products or one in which the by-products are recycled for another process.
Open Question
It was estimated that the eruption of the Mount Pinatubo volcano resulted in the injection of 20 million metric tons of SO2 into the atmosphere. Most of this SO2 underwent oxidation to SO3, which reacts with atmospheric water to form an aerosol. The aerosols caused a 0.5 to 0.6 °C drop in surface temperature in the northern hemisphere. What is the mechanism by which this occurs?
Textbook Question

(a) How are the boundaries between the regions of the atmosphere determined?

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Textbook Question

(b) Explain why the stratosphere, which is about 35 km thick, has a smaller total mass than the troposphere, which is about 12 km thick.

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Textbook Question

Air pollution in the Mexico City metropolitan area is among the worst in the world. The concentration of ozone in Mexico City has been measured at 441 ppb (0.441 ppm). Mexico City sits at an altitude of 7400 feet, which means its atmospheric pressure is only 0.67 atm. (a) Calculate the partial pressure of ozone at 441 ppb if the atmospheric pressure is 0.67 atm.

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