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Ch.18 - Chemistry of the Environment
Chapter 18, Problem 12a

(a) How are the boundaries between the regions of the atmosphere determined?

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Understand that the atmosphere is divided into layers based on temperature gradients and composition.
Identify the main layers of the atmosphere: the troposphere, stratosphere, mesosphere, and thermosphere.
Recognize that the boundaries between these layers, known as 'pauses' (e.g., tropopause, stratopause), are determined by changes in temperature trends.
Note that in the troposphere, temperature decreases with altitude, while in the stratosphere, temperature increases with altitude due to ozone absorption of UV radiation.
Realize that the mesosphere sees a decrease in temperature with altitude, and the thermosphere experiences an increase in temperature with altitude due to solar radiation absorption.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Atmospheric Layers

The atmosphere is divided into distinct layers based on temperature gradients and composition. These layers include the troposphere, stratosphere, mesosphere, thermosphere, and exosphere. Each layer has unique characteristics, such as temperature changes and the presence of specific gases, which help define the boundaries between them.
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Temperature Inversion

Temperature inversion occurs when the temperature increases with altitude, contrary to the normal decrease. This phenomenon can create distinct boundaries between atmospheric layers, as it affects air stability and the mixing of air masses. Inversions are crucial for understanding weather patterns and pollution dispersion.
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Pressure and Density Gradients

The atmosphere's structure is also influenced by pressure and density gradients, which decrease with altitude. These gradients help define the boundaries of atmospheric layers, as different layers exhibit varying densities and pressures. Understanding these gradients is essential for comprehending how air moves and interacts within the atmosphere.
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Related Practice
Open Question
In the following instances, which choice is greener in a chemical process and why? (b) A reagent for the reaction that can be obtained from corn husks or one that is obtained from petroleum. (c) A process that produces no by-products or one in which the by-products are recycled for another process.
Open Question
It was estimated that the eruption of the Mount Pinatubo volcano resulted in the injection of 20 million metric tons of SO2 into the atmosphere. Most of this SO2 underwent oxidation to SO3, which reacts with atmospheric water to form an aerosol. The aerosols caused a 0.5 to 0.6 °C drop in surface temperature in the northern hemisphere. What is the mechanism by which this occurs?
Textbook Question

(a) What is the primary basis for the division of the atmosphere into different regions?

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Textbook Question

(b) Explain why the stratosphere, which is about 35 km thick, has a smaller total mass than the troposphere, which is about 12 km thick.

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Textbook Question

Air pollution in the Mexico City metropolitan area is among the worst in the world. The concentration of ozone in Mexico City has been measured at 441 ppb (0.441 ppm). Mexico City sits at an altitude of 7400 feet, which means its atmospheric pressure is only 0.67 atm. (a) Calculate the partial pressure of ozone at 441 ppb if the atmospheric pressure is 0.67 atm.

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Textbook Question

Air pollution in the Mexico City metropolitan area is among the worst in the world. The concentration of ozone in Mexico City has been measured at 441 ppb (0.441 ppm). Mexico City sits at an altitude of 7400 feet, which means its atmospheric pressure is only 0.67 atm. (b) How many ozone molecules are in 1.0 L of air in Mexico City? Assume T = 25 °C.

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