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Ch.18 - Chemistry of the Environment
Chapter 18, Problem 12a

(a) How are the boundaries between the regions of the atmosphere determined?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Atmospheric Layers

The atmosphere is divided into distinct layers based on temperature gradients and composition. These layers include the troposphere, stratosphere, mesosphere, thermosphere, and exosphere. Each layer has unique characteristics, such as temperature changes and the presence of specific gases, which help define the boundaries between them.
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Temperature Inversion

Temperature inversion occurs when the temperature increases with altitude, contrary to the normal decrease. This phenomenon can create distinct boundaries between atmospheric layers, as it affects air stability and the mixing of air masses. Inversions are crucial for understanding weather patterns and pollution dispersion.
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Pressure and Density Gradients

The atmosphere's structure is also influenced by pressure and density gradients, which decrease with altitude. These gradients help define the boundaries of atmospheric layers, as different layers exhibit varying densities and pressures. Understanding these gradients is essential for comprehending how air moves and interacts within the atmosphere.
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Related Practice
Textbook Question

You are working with an artist who has been commissioned to make a sculpture for a big city in the eastern United States. The artist is wondering what material to use to make her sculpture because she has heard that acid rain in the eastern United States might destroy it over time. You take samples of granite, marble, bronze, and other materials, and place them outdoors for a long time in the big city. You periodically examine the appearance and measure the mass of the samples. (b) What chemical process (or processes) is (are) the most likely responsible for any observed changes in the materials? [Section 18.2]

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Textbook Question

Where does the energy come from to evaporate the esti- mated 425,000 km3 of water that annually leaves the oceans, as illustrated here? [Section 18.3]

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Textbook Question

(a) What is the primary basis for the division of the atmosphere into different regions?

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Textbook Question

(b) Explain why the stratosphere, which is about 35 km thick, has a smaller total mass than the troposphere, which is about 12 km thick.

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Textbook Question

Air pollution in the Mexico City metropolitan area is among the worst in the world. The concentration of ozone in Mexico City has been measured at 441 ppb (0.441 ppm). Mexico City sits at an altitude of 7400 feet, which means its atmospheric pressure is only 0.67 atm. (a) Calculate the partial pressure of ozone at 441 ppb if the atmospheric pressure is 0.67 atm.

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Textbook Question

Air pollution in the Mexico City metropolitan area is among the worst in the world. The concentration of ozone in Mexico City has been measured at 441 ppb (0.441 ppm). Mexico City sits at an altitude of 7400 feet, which means its atmospheric pressure is only 0.67 atm. (b) How many ozone molecules are in 1.0 L of air in Mexico City? Assume T = 25 °C.

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