Ch.9 - Molecular Geometry and Bonding Theories
Chapter 9, Problem 120b
The organic molecules shown here are derivatives of benzene in which six-membered rings are 'fused' at the edges of the hexagons.
(b) Suppose you are given a sample of one of the compounds. Could combustion analysis be used to determine unambiguously which of the three it is?
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Related Practice
Textbook Question
The phosphorus trihalides 1PX32 show the following variation
in the bond angle X¬P¬X: PF3, 96.3°; PCl3, 100.3°;
PBr3, 101.0°; PI3, 102.0°. The trend is generally attributed
to the change in the electronegativity of the halogen.
(b) What is the general trend in the X¬P¬X
angle as the halide electronegativity increases?
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Textbook Question
Many compounds of the transition-metal elements contain
direct bonds between metal atoms. We will assume
that the z-axis is defined as the metal–metal bond axis.
(d) Sketch the energylevel
diagram for the Sc2 molecule, assuming that only the
3d orbital from part (a) is important.
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Textbook Question
The organic molecules shown here are derivatives of benzene
in which six-membered rings are 'fused' at the edges
of the hexagons.
(e) Benzene, naphthalene, and anthracene
are colorless, but tetracene is orange. What does this imply
about the relative HOMO–LUMO energy gaps in these molecules?
See the 'Chemistry Put to Work' box on orbitals
and energy.
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Textbook Question
Methyl isocyanate, CH3NCO, was made infamous in 1984 when an accidental leakage of this compound from a storage tank in Bhopal, India, resulted in the deaths of about 3800 people and severe and lasting injury to many thousands more. (a) Draw a Lewis structure for methyl isocyanate.
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