Skip to main content
Ch.9 - Molecular Geometry and Bonding Theories

Chapter 9, Problem 119

Many compounds of the transition-metal elements contain direct bonds between metal atoms. We will assume that the z-axis is defined as the metal–metal bond axis. (d) Sketch the energylevel diagram for the Sc2 molecule, assuming that only the 3d orbital from part (a) is important.

Verified Solution
Video duration:
3m
This video solution was recommended by our tutors as helpful for the problem above.
353
views
Was this helpful?

Video transcript

Hello everyone. So in this video we're going to go ahead and write the molecular orbital energy diagram for T. I. To I'm assuming that this orbital is important. So let's first go ahead and write the valence electron configuration for our element. So the surveillance electron configuration of our specify a little bit of our element. That's going to be during the shorthand version. So our gun will be our noble guests. And then continuing the electron configuration, we have four S two and three D. Two. So because we have two atoms here, the total Valence electron is going to be eight. So these two are advanced electrons. We have a total of them. Alright, so now drawing out the molecular orbital energy diagram, of course going up is our energy simplify that to E. Then we have at the bottom are sigma for us. Over to the left, we have our for us to the right, we have again for us and then on top of the sigma star for us and then right on top we'll have our sigma three D To the left and the right will have three d. c. And finally on top over Sigma Star three D. And again because we have eight electrons that we need to go ahead and write it in here. We're gonna go from bottom to the top because of Hansbrough. So let's go ahead and do that. And of course let's not forget this as well. This is the proper diagram format. All right. So then the question again is asking us to write the molecular orbital energy diagram and we're able to do this right over here. So all this is going to be the answer for this question. Thank you all so much for watching.
Related Practice
Textbook Question

Sulfur tetrafluoride (SF4) reacts slowly with O2 to form sulfur tetrafluoride monoxide (OSF4) according to the following unbalanced reaction: SF4(g) + O2(g) → OSF4(g) The O atom and the four F atoms in OSF4 are bonded to a central S atom. (c) Use average bond enthalpies (Table 8.3) to estimate the enthalpy of the reaction. Is it endothermic or exothermic?

688
views
Textbook Question

Sulfur tetrafluoride 1SF42 reacts slowly with O2 to form sulfur

tetrafluoride monoxide 1OSF42 according to the following

unbalanced reaction:

SF41g2 + O21g2¡OSF41g2

The O atom and the four F atoms in OSF4 are bonded to a

central S atom.

(e) For each of the molecules you drew in part (d), state how many

fluorines are equatorial and how many are axial.

101
views
Textbook Question
The phosphorus trihalides 1PX32 show the following variation in the bond angle X¬P¬X: PF3, 96.3°; PCl3, 100.3°; PBr3, 101.0°; PI3, 102.0°. The trend is generally attributed to the change in the electronegativity of the halogen. (b) What is the general trend in the X¬P¬X angle as the halide electronegativity increases?
1453
views
Textbook Question
The organic molecules shown here are derivatives of benzene in which six-membered rings are 'fused' at the edges of the hexagons.

(e) Benzene, naphthalene, and anthracene are colorless, but tetracene is orange. What does this imply about the relative HOMO–LUMO energy gaps in these molecules? See the 'Chemistry Put to Work' box on orbitals and energy.
644
views
Textbook Question

The organic molecules shown here are derivatives of benzene in which six-membered rings are 'fused' at the edges of the hexagons.

(b) Suppose you are given a sample of one of the compounds. Could combustion analysis be used to determine unambiguously which of the three it is?

461
views
Textbook Question

Methyl isocyanate, CH3NCO, was made infamous in 1984 when an accidental leakage of this compound from a storage tank in Bhopal, India, resulted in the deaths of about 3800 people and severe and lasting injury to many thousands more. (a) Draw a Lewis structure for methyl isocyanate.

970
views