Chapter 9, Problem 114b
Sulfur tetrafluoride (SF4) reacts slowly with O2 to form sulfur tetrafluoride monoxide (OSF4) according to the following unbalanced reaction: SF4(g) + O2(g) → OSF4(g) The O atom and the four F atoms in OSF4 are bonded to a central S atom. (b) Write a Lewis structure of OSF4 in which the formal charges of all atoms are zero.
Video transcript
The energy-level diagram in Figure 9.36 shows that the sideways overlap of a pair of p orbitals produces two molecular orbitals, one bonding and one antibonding. In ethylene there is a pair of electrons in the bonding π orbital between the two carbons. Absorption of a photon of the appropriate wavelength can result in promotion of one of the bonding electrons from the p2p to the p*2p molecular orbital. (b) Assuming this electronic transition corresponds to the HOMO-LUMO transition, what is the LUMO in ethylene?
The energy-level diagram in Figure 9.36 shows that the sideways overlap of a pair of p orbitals produces two molecular orbitals, one bonding and one antibonding. In ethylene there is a pair of electrons in the bonding π orbital between the two carbons. Absorption of a photon of the appropriate wavelength can result in promotion of one of the bonding electrons from the p2p to the p*2p molecular orbital. (c) Is the C¬C bond in ethylene stronger or weaker in the excited state than in the ground state? Why?
Sulfur tetrafluoride 1SF42 reacts slowly with O2 to form sulfur tetrafluoride monoxide 1OSF42 according to the following unbalanced reaction: SF41g2 + O21g2¡OSF41g2 The O atom and the four F atoms in OSF4 are bonded to a central S atom. (a) Balance the equation.
Sulfur tetrafluoride (SF4) reacts slowly with O2 to form sulfur tetrafluoride monoxide (OSF4) according to the following unbalanced reaction: SF4(g) + O2(g) → OSF4(g) The O atom and the four F atoms in OSF4 are bonded to a central S atom. (c) Use average bond enthalpies (Table 8.3) to estimate the enthalpy of the reaction. Is it endothermic or exothermic?
Sulfur tetrafluoride 1SF42 reacts slowly with O2 to form sulfur
tetrafluoride monoxide 1OSF42 according to the following
unbalanced reaction:
SF41g2 + O21g2¡OSF41g2
The O atom and the four F atoms in OSF4 are bonded to a
central S atom.
(e) For each of the molecules you drew in part (d), state how many
fluorines are equatorial and how many are axial.