Consider the molecule PF4Cl. (c) Predict the molecular geometry of PF4Cl. How did your answer for part (b) influence your answer here in part (c)?
Ch.9 - Molecular Geometry and Bonding Theories
Chapter 9, Problem 90
Fill in the blank spaces in the following chart. If the molecule column is blank, find an example that fulfills the conditions of the rest of the row. Molecule Electron-Domain Hybridization Dipole Geometry of Central Atom Moment? Yes or No CO2 sp3 Yes sp3 No Trigonal planar No SF4 Octahedral No sp2 Yes Trigonal bipyramidal No XeF2 Complete the first row of the table.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Electron-Domain Hybridization
Electron-domain hybridization is the process by which atomic orbitals mix to form new hybrid orbitals that can accommodate the electron pairs around a central atom. The type of hybridization (e.g., sp, sp2, sp3) depends on the number of electron domains, which include bonding pairs and lone pairs. Understanding this concept is crucial for predicting molecular geometry and the arrangement of atoms in a molecule.
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Hybridization and Electron Geometry
Molecular Geometry
Molecular geometry refers to the three-dimensional arrangement of atoms in a molecule, which is determined by the repulsion between electron pairs surrounding the central atom. The VSEPR (Valence Shell Electron Pair Repulsion) theory helps predict the geometry based on the number of bonding and lone pairs. This concept is essential for understanding the shape and polarity of molecules, which influences their chemical behavior.
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Dipole Moment
A dipole moment is a measure of the separation of positive and negative charges in a molecule, indicating its polarity. It arises when there is an uneven distribution of electron density, often due to differences in electronegativity between bonded atoms. Understanding dipole moments is important for predicting molecular interactions, solubility, and reactivity, as polar molecules behave differently than nonpolar ones.
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Related Practice
Textbook Question
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Textbook Question
Consider the molecule PF4Cl. (d) Would you expect the molecule to distort from its ideal electron-domain geometry? If so, how would it distort?
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Textbook Question
Although I3- is a known ion, F3- is not. (d) Yet another classmate says F3- does not exist because F is too small to make bonds to more than one atom. Is this classmate possibly correct?
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Textbook Question
Ethyl propanoate, CH3CH2COOCH2CH3, gives a fruity pineapple-like smell. (e) What are the approximate bond angles around each carbon atom in the molecule?
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Textbook Question
An AB5 molecule adopts the geometry shown here. (b) Do you think there are any nonbonding electron pairs on atom A?
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Textbook Question
An AB5 molecule adopts the geometry shown here. (c) Suppose the B atoms are halogen atoms. Of which group in the periodic table is atom A a member: (i) Group 15, (ii) Group 16, (iii) Group 17, (iv) Group 18, or (v) More information is needed?
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