Chapter 9, Problem 92e
Ethyl propanoate, CH3CH2COOCH2CH3, gives a fruity pineapple-like smell. (e) What are the approximate bond angles around each carbon atom in the molecule?
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Consider the molecule PF4Cl. (d) Would you expect the molecule to distort from its ideal electron-domain geometry? If so, how would it distort?
Fill in the blank spaces in the following chart. If the molecule column is blank, find an example that fulfills the conditions of the rest of the row. Molecule Electron-Domain Hybridization Dipole Geometry of Central Atom Moment? Yes or No CO2 sp3 Yes sp3 No Trigonal planar No SF4 Octahedral No sp2 Yes Trigonal bipyramidal No XeF2 Complete the first row of the table.
An AB5 molecule adopts the geometry shown here. (b) Do you think there are any nonbonding electron pairs on atom A?
An AB5 molecule adopts the geometry shown here. (c) Suppose the B atoms are halogen atoms. Of which group in the periodic table is atom A a member: (i) Group 15, (ii) Group 16, (iii) Group 17, (iv) Group 18, or (v) More information is needed?
The O¬H bond lengths in the water molecule 1H2O2 are 96 pm, and the H¬O¬H angle is 104.5°. The dipole moment of the water molecule is 1.85 D. (b) Calculate the magnitude of the bond dipole of the O¬H bonds. (Note: You will need to use vector addition to do this.)