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Ch.9 - Molecular Geometry and Bonding Theories
Chapter 9, Problem 88c

Consider the molecule PF4Cl. (c) Predict the molecular geometry of PF4Cl. How did your answer for part (b) influence your answer here in part (c)?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

VSEPR Theory

Valence Shell Electron Pair Repulsion (VSEPR) Theory is a model used to predict the geometry of molecules based on the repulsion between electron pairs surrounding a central atom. According to VSEPR, electron pairs, whether bonding or lone pairs, will arrange themselves to minimize repulsion, leading to specific molecular shapes. For PF4Cl, the presence of five regions of electron density (four P-F bonds and one P-Cl bond) will determine its geometry.
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Molecular Geometry

Molecular geometry refers to the three-dimensional arrangement of atoms within a molecule. It is influenced by the number of bonding pairs and lone pairs of electrons around the central atom. In the case of PF4Cl, the molecular geometry can be predicted as trigonal bipyramidal due to the five bonding pairs, which affects the angles and overall shape of the molecule.
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Influence of Hybridization

Hybridization is the concept of mixing atomic orbitals to form new hybrid orbitals that can accommodate bonding. In PF4Cl, the phosphorus atom undergoes sp3d hybridization to form five equivalent orbitals for bonding with four fluorine atoms and one chlorine atom. Understanding hybridization helps in predicting the molecular geometry and bond angles, as it directly relates to the arrangement of electron pairs around the central atom.
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