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Ch.9 - Molecular Geometry and Bonding Theories
Chapter 9, Problem 13c

(c) Is XeF2 linear

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Molecular Geometry

Molecular geometry refers to the three-dimensional arrangement of atoms within a molecule. It is determined by the number of bonding pairs and lone pairs of electrons around the central atom, which influence the shape due to repulsion between electron pairs. Understanding molecular geometry is crucial for predicting the physical and chemical properties of substances.
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VSEPR Theory

Valence Shell Electron Pair Repulsion (VSEPR) theory is a model used to predict the geometry of individual molecules based on the repulsion between electron pairs in the valence shell of the central atom. According to VSEPR, electron pairs will arrange themselves to minimize repulsion, leading to specific molecular shapes, such as linear, trigonal planar, or tetrahedral.
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Hybridization

Hybridization is the concept of mixing atomic orbitals to form new hybrid orbitals that can accommodate bonding. In the case of XeF2, the xenon atom undergoes sp3d hybridization, which allows it to form two bonds with fluorine atoms while maintaining three lone pairs. This hybridization is essential for understanding the linear arrangement of the molecule.
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