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Ch.8 - Basic Concepts of Chemical Bonding
Chapter 8, Problem 102d

One scale for electronegativity is based on the concept that the electronegativity of any atom is proportional to the ionization energy of the atom minus its electron affinity: electronegativity = k1I - EA2, where k is a proportionality constant. (d) Use your result from part (c) to determine the electronegativities of Cl and O using this scale. Use your result to determine the electronegativity of Cl using this scale.

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Step 1: The first step is to understand the formula given. The electronegativity of an atom is given by the formula: electronegativity = k(I - EA), where I is the ionization energy, EA is the electron affinity, and k is a proportionality constant.
Step 2: To find the electronegativity of Chlorine (Cl) and Oxygen (O), you need to know their ionization energies and electron affinities. These values can be found in a standard chemistry reference book or online.
Step 3: Once you have the ionization energy and electron affinity for each atom, substitute these values into the formula. Remember to use the same units for both values.
Step 4: The proportionality constant, k, is the same for all atoms. Therefore, you can compare the electronegativities of different atoms even if you don't know the exact value of k.
Step 5: After substituting the values into the formula, you will get the electronegativity of each atom. The atom with the higher electronegativity is more likely to attract electrons.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electronegativity

Electronegativity is a measure of an atom's ability to attract and hold onto electrons when forming chemical bonds. It is a key factor in determining the nature of bonds between atoms, influencing molecular polarity and reactivity. The scale of electronegativity helps predict how electrons are distributed in a molecule, affecting its chemical properties.
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Ionization Energy

Ionization energy is the energy required to remove an electron from an isolated atom in its gaseous state. It reflects how strongly an atom holds onto its electrons; higher ionization energy indicates a stronger attraction. This property is crucial for understanding electronegativity, as atoms with higher ionization energies tend to have higher electronegativities.
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Electron Affinity

Electron affinity is the amount of energy released when an electron is added to a neutral atom in the gas phase. It indicates how much an atom wants to gain an electron. A higher electron affinity means that an atom is more likely to attract additional electrons, which plays a significant role in determining its electronegativity.
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Related Practice
Open Question
You and a partner are asked to complete a lab entitled “Carbonates of Group 2 metal” that is scheduled to extend over two lab periods. The first lab, which is to be completed by your partner, is devoted to carrying out compositional analysis and determining the identity of the Group 2 metal (M). In the second lab, you are to determine the melting point of this compound. Upon going to the lab, you find two unlabeled vials containing white powder. You also find the following notes in your partner’s notebook—Compound 1: 40.04% M, 12.00% C, and 47.96% O (by mass); Compound 2: 69.59% M, 6.09% C, and 24.32% O (by mass). (a) What is the empirical formula for Compound 1 and the identity of M? (b) What is the empirical formula for Compound 2 and the identity of M? Upon determining the melting points of these two compounds, you find that both compounds do not melt up to the maximum temperature of your apparatus; instead, the compounds decompose and liberate a colorless gas. (c) What is the identity of the colorless gas?
Textbook Question

One scale for electronegativity is based on the concept that the electronegativity of any atom is proportional to the ionization energy of the atom minus its electron affinity: electronegativity = k1I - EA2, where k is a proportionality constant. (b) Why are both ionization energy and electron affinity relevant to the notion of electronegativity?

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Textbook Question

One scale for electronegativity is based on the concept that the electronegativity of any atom is proportional to the ionization energy of the atom minus its electron affinity: electronegativity = k1I - EA2, where k is a proportionality constant. (c) By using data in Chapter 7, determine the value of k that would lead to an electronegativity of 4.0 for F under this definition.

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Open Question
The compound chloral hydrate, known in detective stories as knockout drops, is composed of 14.52% C, 1.83% H, 64.30% Cl, and 13.35% O by mass, and has a molar mass of 165.4 g/mol. (c) Draw the Lewis structure of the molecule, assuming that the Cl atoms bond to a single C atom and that there are a C–C bond and two C–O bonds in the compound.
Open Question
Potassium peroxide is composed of 70.96% K and 29.04% O. Each peroxide ion has a net charge of 2-. (a) Given the molecular weight of the compound is 110.19, determine the chemical formula of potassium peroxide.
Textbook Question

Acetylene (C2H2) and nitrogen (N2) both contain a triple bond, but they differ greatly in their chemical properties. (b) By referring to Appendix C, look up the enthalpies of formation of acetylene and nitrogen. Which compound is more stable?

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