Chapter 8, Problem 105b
Acetylene (C2H2) and nitrogen (N2) both contain a triple bond, but they differ greatly in their chemical properties. (b) By referring to Appendix C, look up the enthalpies of formation of acetylene and nitrogen. Which compound is more stable?
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One scale for electronegativity is based on the concept that the electronegativity of any atom is proportional to the ionization energy of the atom minus its electron affinity: electronegativity = k1I - EA2, where k is a proportionality constant. (b) Why are both ionization energy and electron affinity relevant to the notion of electronegativity?
One scale for electronegativity is based on the concept that the electronegativity of any atom is proportional to the ionization energy of the atom minus its electron affinity: electronegativity = k1I - EA2, where k is a proportionality constant. (c) By using data in Chapter 7, determine the value of k that would lead to an electronegativity of 4.0 for F under this definition.
One scale for electronegativity is based on the concept that the electronegativity of any atom is proportional to the ionization energy of the atom minus its electron affinity: electronegativity = k1I - EA2, where k is a proportionality constant. (d) Use your result from part (c) to determine the electronegativities of Cl and O using this scale. Use your result to determine the electronegativity of Cl using this scale.
Under special conditions, sulfur reacts with anhydrous liquid ammonia to form a binary compound of sulfur and nitrogen. The compound is found to consist of 69.6% S and 30.4% N. Measurements of its molecular mass yield a value of 184.3 g/mol. The compound occasionally detonates on being struck or when heated rapidly. The sulfur and nitrogen atoms of the molecule are joined in a ring. All the bonds in the ring are of the same length. (a) Calculate the empirical and molecular formulas for the substance.
A common form of elemental phosphorus is the tetrahedral P4 molecule, where all four phosphorus atoms are equivalent:
(b) How many P-P bonds are there in the molecule?
A common form of elemental phosphorus is the tetrahedral P4 molecule, where all four phosphorus atoms are equivalent:
Draw a Lewis structure for a linear P4 molecule that satisfies the octet rule. Does this molecule have resonance structures?