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Ch.8 - Basic Concepts of Chemical Bonding

Chapter 8, Problem 88c

A major challenge in implementing the 'hydrogen economy' is finding a safe, lightweight, and compact way of storing hydrogen for use as a fuel. The hydrides of light metals are attractive for hydrogen storage because they can store a high weight percentage of hydrogen in a small volume. For example, NaAlH4 can release 5.6% of its mass as H2 upon decomposing to NaH(s), Al(s), and H2(g). NaAlH4 possesses both covalent bonds, which hold polyatomic anions together, and ionic bonds. (c) Based on electronegativity differences, predict the identity of the polyatomic anion. Draw a Lewis structure for this ion.

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Hi everyone here we have a question telling us that sodium Borough hydride has Covalin bonds that bind poly atomic and ions together. It also has ionic bonds. And we want to make a prediction on the poly atomic and ions identity based on variations of the electro negativity. So we know that polly atomic ions are held together by Covalin bonds. So let's look at some of the possible Covalin bonds for sodium Borough hydride. We have sodium and hydrogen or we have boron and hydrogen. So let's look at our difference in electro negativity. So sodium hydrogen electro negativity ease Equals the absolute value of 0.9 -2.2, which is -1.3. And then we have boron and hydrogen electro negativity ease. And that equals the absolute value of 2 -2.2 Or 2.2, Which equals 0.2. So we want to find the smaller electro negative difference which in this case is four on hydrogen. The smaller electro negative Prince means that it is more Covalin and because it is more Covalin that is more likely that it is the poly atomic ion. So our poly atomic ion is B. H. Four. And that is our final answer. Thank you for watching. Bye.
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Textbook Question

(b) Using these partial charges and the atomic radii given in Figure 7.8, estimate the dipole moment of the molecule.

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Textbook Question

(c) The measured dipole moment of BrCl is 0.57 D. If you assume the bond length in BrCl is the sum of the atomic radii, what are the partial charges on the atoms in BrCl using the experimental dipole moment?

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Textbook Question

A major challenge in implementing the 'hydrogen economy' is finding a safe, lightweight, and compact way of storing hydrogen for use as a fuel. The hydrides of light metals are attractive for hydrogen storage because they can store a high weight percentage of hydrogen in a small volume. For example, NaAlH4 can release 5.6% of its mass as H2 upon decomposing to NaH(s), Al(s), and H2(g). NaAlH4 possesses both covalent bonds, which hold polyatomic anions together, and ionic bonds. (b) Which element in NaAlH4 is the most electronegative? Which one is the least electronegative? Which element in NaAlH4 is the least electronegative?

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Textbook Question

A major challenge in implementing the 'hydrogen economy' is finding a safe, lightweight, and compact way of storing hydrogen for use as a fuel. The hydrides of light metals are attractive for hydrogen storage because they can store a high weight percentage of hydrogen in a small volume. For example, NaAlH4 can release 5.6% of its mass as H2 upon decomposing to NaH(s), Al(s), and H2(g). NaAlH4 possesses both covalent bonds, which hold polyatomic anions together, and ionic bonds. (d) What is the formal charge on hydrogen in the polyatomic ion?

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Textbook Question

Although I3- is a known ion, F3- is not. (c) Another classmate says F3- does not exist because it would violate the octet rule. Is this classmate possibly correct?

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Textbook Question

The hypochlorite ion, ClO-, is the active ingredient in bleach. The perchlorate ion, ClO4-, is a main component of rocket propellants. Draw Lewis structures for both ions. (b) What is the formal charge of Cl in the perchlorate ion, assuming the Cl—O bonds are all single bonds?

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