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Ch.6 - Electronic Structure of Atoms
Chapter 6, Problem 42a

The Lyman series of emission lines of the hydrogen atom are those for which nf = 1. (a) Determine the region of the electromagnetic spectrum in which the lines of the Lyman series are observed.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Lyman Series

The Lyman series refers to a set of spectral lines corresponding to transitions of electrons in a hydrogen atom from higher energy levels (n ≥ 2) to the lowest energy level (n = 1). These transitions result in the emission of ultraviolet light, which is a key feature of hydrogen's emission spectrum.
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Electromagnetic Spectrum

The electromagnetic spectrum encompasses all types of electromagnetic radiation, arranged by wavelength or frequency. It includes gamma rays, X-rays, ultraviolet light, visible light, infrared radiation, microwaves, and radio waves. The Lyman series specifically falls within the ultraviolet region of this spectrum.
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Energy Level Transitions

Energy level transitions in an atom occur when an electron moves between different energy states. When an electron drops from a higher energy level to a lower one, it releases energy in the form of a photon. The energy of the emitted photon corresponds to the difference in energy between the two levels, determining the wavelength and thus the position in the electromagnetic spectrum.
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Related Practice
Textbook Question

(a) Using Equation 6.5, calculate the energy of an electron in the hydrogen atom when n = 3 and when n = 6. Calculate the wavelength of the radiation released when an electron moves from n = 6 to n = 3. when n = 6

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Textbook Question

The visible emission lines observed by Balmer all involved nf = 2. (a) Which of the following is the best explanation of why the lines with nf = 3 are not observed in the visible portion of the spectrum: (i) Transitions to nf = 3 are not allowed to happen, (ii) transitions to nf = 3 emit photons in the infrared portion of the spectrum, (iii) transitions to nf = 3 emit photons in the ultraviolet portion of the spectrum, or (iv) transitions to nf = 3 emit photons that are at exactly the same wavelengths as those to nf = 2.

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Textbook Question

The visible emission lines observed by Balmer all involved nf = 2. (b) Calculate the wavelengths of the first three lines in the Balmer series—those for which ni = 3, 4, and 5—and identify these lines in the emission spectrum shown in Figure 6.11.

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Textbook Question

The Lyman series of emission lines of the hydrogen atom are those for which nf = 1. (b) Calculate the wavelengths of the first three lines in the Lyman series—those for which ni = 2, 3, and 4.

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Textbook Question

One of the emission lines of the hydrogen atom has a wavelength of 94.974 nm. (a) In what region of the electromagnetic spectrum is this emission found?

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Textbook Question

One of the emission lines of the hydrogen atom has a wavelength of 94.974 nm. (b) Determine the initial and final values of n associated with this emission.

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