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Ch.6 - Electronic Structure of Atoms
Chapter 6, Problem 33b

Molybdenum metal must absorb radiation with an energy higher than 7.22 * 10-19 J ('energy threshold') before it can eject an electron from its surface via the photoelectric effect. (b) What wavelength of radiation will provide a photon of this energy?

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Identify the relationship between energy and wavelength using the equation: \( E = \frac{hc}{\lambda} \), where \( E \) is the energy of the photon, \( h \) is Planck's constant \( 6.626 \times 10^{-34} \text{ J s} \), \( c \) is the speed of light \( 3.00 \times 10^8 \text{ m/s} \), and \( \lambda \) is the wavelength.
Rearrange the equation to solve for wavelength \( \lambda \): \( \lambda = \frac{hc}{E} \).
Substitute the given energy threshold \( E = 7.22 \times 10^{-19} \text{ J} \) into the equation.
Substitute the values for Planck's constant \( h \) and the speed of light \( c \) into the equation.
Calculate the wavelength \( \lambda \) using the substituted values to find the wavelength of radiation that provides a photon of the given energy.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Photoelectric Effect

The photoelectric effect is a phenomenon where electrons are emitted from a material when it absorbs light or radiation of sufficient energy. This effect demonstrates the particle nature of light, as photons must have energy exceeding a certain threshold to dislodge electrons from the surface of a material, which is specific to each element.
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Photoelectric Effect

Energy of a Photon

The energy of a photon is directly related to its frequency and inversely related to its wavelength, described by the equation E = hν = hc/λ, where E is energy, h is Planck's constant, ν is frequency, c is the speed of light, and λ is wavelength. This relationship is crucial for determining the wavelength of radiation needed to achieve a specific energy threshold.
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Photon Energy Formulas

Planck's Constant

Planck's constant (h) is a fundamental constant in quantum mechanics, valued at approximately 6.626 x 10^-34 J·s. It relates the energy of a photon to its frequency, serving as a bridge between the macroscopic and quantum worlds. Understanding this constant is essential for calculating the energy of photons in the context of the photoelectric effect.
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Related Practice
Textbook Question

A diode laser emits at a wavelength of 987 nm. (a) In what portion of the electromagnetic spectrum is this radiation found? (b) All of its output energy is absorbed in a detector that measures a total energy of 0.52 J over a period of 32 s. How many photons per second are being emitted by the laser?

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Textbook Question

A stellar object is emitting radiation at 3.0 mm. (a) What type of electromagnetic spectrum is this radiation (b) If a detector is capturing 3.0 3 108 photons per second at this wavelength, what is the total energy of the photons detected in 1 day?

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Textbook Question

Molybdenum metal must absorb radiation with an energy higher than 7.22 * 10-19 J ('energy threshold') before it can eject an electron from its surface via the photoelectric effect. (a) What is the frequency threshold for emission of electrons?

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Textbook Question

Molybdenum metal must absorb radiation with an energy higher than 7.22 * 10-19 J ('energy threshold') before it can eject an electron from its surface via the photoelectric effect. (c) If molybdenum is irradiated with light of wavelength of 240 nm, what is the maximum possible velocity of the emitted electrons?

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Open Question
Titanium metal requires light with a maximum wavelength of 286 nm to emit electrons. (a) What is the minimum energy of the photons necessary to emit electrons from titanium via the photoelectric effect? (b) If titanium is irradiated with light of wavelength 276 nm, what is the maximum possible kinetic energy of the emitted electrons?
Textbook Question

Does the hydrogen atom 'expand' or 'contract' when an electron is excited from the n = 1 state to the n = 3 state?

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