Skip to main content
Ch.6 - Electronic Structure of Atoms
Chapter 6, Problem 24

Einstein's 1905 paper on the photoelectric effect was the first important application of Planck's quantum hypothesis. Describe Planck's original hypothesis, and explain how Einstein made use of it in his theory of the photoelectric effect.

Verified Solution

Video duration:
2m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Planck's Quantum Hypothesis

Max Planck proposed that energy is quantized, meaning it can only be emitted or absorbed in discrete units called 'quanta' or 'photons.' This hypothesis was revolutionary as it challenged classical physics, which treated energy as a continuous quantity. Planck's work laid the foundation for quantum mechanics, suggesting that the energy of electromagnetic radiation is proportional to its frequency.
Recommended video:
Guided course
00:50
Photons and Planck's Constant

Photoelectric Effect

The photoelectric effect refers to the phenomenon where electrons are emitted from a material, typically a metal, when it is exposed to light of sufficient frequency. Classical wave theory could not explain why light below a certain frequency failed to eject electrons, regardless of its intensity. Einstein's explanation of this effect demonstrated that light behaves as both a wave and a particle, supporting Planck's quantum hypothesis.
Recommended video:
Guided course
01:26
Photoelectric Effect

Energy-Frequency Relationship

Einstein built on Planck's hypothesis by establishing a direct relationship between the energy of a photon and its frequency, expressed by the equation E = hf, where E is energy, h is Planck's constant, and f is frequency. This relationship explains why only light above a certain frequency can cause the photoelectric effect, as the energy of the photons must be sufficient to overcome the work function of the material to release electrons.
Recommended video:
Guided course
00:31
Frequency-Wavelength Relationship