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Ch.6 - Electronic Structure of Atoms
Chapter 6, Problem 89d

Consider a transition in which the electron of a hydrogen atom is excited from n = 1 to n = . (d) How are the results of parts (b) and (c) related to the plot shown in Exercise 6.88?
Graph showing electron kinetic energy versus frequency, illustrating transitions in hydrogen atom.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Quantum Energy Levels

In quantum mechanics, electrons in an atom occupy discrete energy levels, denoted by quantum numbers (n). For hydrogen, these levels are quantized, meaning an electron can only exist in specific states. The transition from a lower level (n=1) to a higher level (n=2, 3, etc.) involves the absorption of energy, typically in the form of a photon, which corresponds to the energy difference between these levels.
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Photon Energy and Frequency

The energy of a photon is directly related to its frequency through the equation E = hν, where E is energy, h is Planck's constant, and ν is frequency. When an electron transitions between energy levels, it absorbs or emits a photon with energy equal to the difference between the two levels. This relationship is crucial for understanding how the frequency of light corresponds to specific electronic transitions in atoms.
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Kinetic Energy and Electron Transitions

The kinetic energy of an electron in an atom can change during electronic transitions. When an electron absorbs energy and moves to a higher energy level, it may also gain kinetic energy, which is reflected in the graph. The plot illustrates how the kinetic energy of the electron increases with frequency, indicating that only photons with sufficient energy (above a threshold frequency, ν₀) can cause transitions that result in increased kinetic energy.
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Related Practice
Textbook Question

In an experiment to study the photoelectric effect, a scientist measures the kinetic energy of ejected electrons as a function of the frequency of radiation hitting a metal surface. She obtains the following plot. The point labeled 'n0' corresponds to light with a wavelength of 542 nm. (a) What is the value of n0 in s - 1?

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Textbook Question

Consider a transition in which the electron of a hydrogen atom is excited from n = 1 to n = . (a) What is the end result of this transition?

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Textbook Question

Consider a transition in which the electron of a hydrogen atom is excited from n = 1 to n = . (b) What is the wavelength of light that must be absorbed to accomplish this process?

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Textbook Question

The human retina has three types of receptor cones, each sensitive to a different range of wavelengths of visible light, as shown in this figure (the colors are merely to differentiate the three curves from one another; they do not indicate the actual colors represented by each curve):

(c) Explain why the sky appears blue even though all wavelengths of solar light are scattered by the atmosphere.

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Textbook Question

The series of emission lines of the hydrogen atom for which nf = 3 is called the Paschen series. (a) Determine the region of the electromagnetic spectrum in which the lines of the Paschen series are observed.

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Textbook Question

The series of emission lines of the hydrogen atom for which nf = 3 is called the Paschen series. (b) Calculate the wavelengths of the first three lines in the Paschen series—those for which ni = 4, 5, and 6.

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