Chapter 4, Problem 84
The distinctive odor of vinegar is due to acetic acid, CH3COOH, which reacts with sodium hydroxide according to: CH3COOH1aq2 + NaOH1aq2¡ H2O1l2 + NaCH3COO1aq2 If 3.45 mL of vinegar needs 42.5 mL of 0.115 M NaOH to reach the equivalence point in a titration, how many grams of acetic acid are in a 1.00-qt sample of this vinegar?
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(a) How many milliliters of 0.120 M HCl are needed to completely neutralize 50.0 mL of 0.101 M Ba(OH)2 solution?
(b) How many milliliters of 0.125 M H2SO4 are needed to neutralize 0.200 g of NaOH?
(c) If 55.8 mL of a BaCl2 solution is needed to precipitate all the sulfate ion in a 752-mg sample of Na2SO4, what is the molarity of the BaCl2 solution?
A 4.36-g sample of an unknown alkali metal hydroxide is dissolved in 100.0 mL of water. An acid–base indicator is added, and the resulting solution is titrated with 2.50 M HCl(aq) solution. The indicator changes color, signaling that the equivalence point has been reached, after 17.0 mL of the hydrochloric acid solution has been added. (a) What is the molar mass of the metal hydroxide?
A 4.36-g sample of an unknown alkali metal hydroxide is dissolved in 100.0 mL of water. An acid–base indicator is added, and the resulting solution is titrated with 2.50 M HCl(aq) solution. The indicator changes color, signaling that the equivalence point has been reached, after 17.0 mL of the hydrochloric acid solution has been added. (b) What is the identity of the alkali metal cation: Li+, Na+, K+, Rb+, or Cs+?
An 8.65-g sample of an unknown group 2 metal hydroxide is dissolved in 85.0 mL of water. An acid–base indicator is added and the resulting solution is titrated with 2.50 M HCl(aq) solution. The indicator changes color, signaling that the equivalence point has been reached, after 56.9 mL of the hydrochloric acid solution has been added. (b) What is the identity of the metal cation: Ca2+, Sr2+, or Ba2+?