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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 84

The distinctive odor of vinegar is due to acetic acid, CH3COOH, which reacts with sodium hydroxide according to: CH3COOH1aq2 + NaOH1aq2¡ H2O1l2 + NaCH3COO1aq2 If 3.45 mL of vinegar needs 42.5 mL of 0.115 M NaOH to reach the equivalence point in a titration, how many grams of acetic acid are in a 1.00-qt sample of this vinegar?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Titration

Titration is a quantitative analytical technique used to determine the concentration of a solute in a solution. It involves the gradual addition of a titrant, a solution of known concentration, to a sample until the reaction reaches the equivalence point, where the amount of titrant equals the amount of substance in the sample. This method is commonly used in acid-base reactions to find the concentration of acids or bases.
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Molarity

Molarity is a measure of concentration defined as the number of moles of solute per liter of solution. It is expressed in moles per liter (M) and is crucial for calculations in titration, as it allows for the determination of how much of a reactant is needed to react with a given amount of another substance. Understanding molarity is essential for converting volumes and concentrations during titration calculations.
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Stoichiometry

Stoichiometry is the branch of chemistry that deals with the relationships between the quantities of reactants and products in a chemical reaction. It is based on the balanced chemical equation, which provides the mole ratios needed to calculate the amounts of substances involved. In the context of the titration question, stoichiometry is used to relate the volume and concentration of sodium hydroxide to the amount of acetic acid present in the vinegar.
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Related Practice
Textbook Question

(a) How many milliliters of 0.120 M HCl are needed to completely neutralize 50.0 mL of 0.101 M Ba(OH)2 solution?

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Textbook Question

(b) How many milliliters of 0.125 M H2SO4 are needed to neutralize 0.200 g of NaOH?

805
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Textbook Question

(c) If 55.8 mL of a BaCl2 solution is needed to precipitate all the sulfate ion in a 752-mg sample of Na2SO4, what is the molarity of the BaCl2 solution?

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Textbook Question

A 4.36-g sample of an unknown alkali metal hydroxide is dissolved in 100.0 mL of water. An acid–base indicator is added, and the resulting solution is titrated with 2.50 M HCl(aq) solution. The indicator changes color, signaling that the equivalence point has been reached, after 17.0 mL of the hydrochloric acid solution has been added. (a) What is the molar mass of the metal hydroxide?

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Textbook Question

A 4.36-g sample of an unknown alkali metal hydroxide is dissolved in 100.0 mL of water. An acid–base indicator is added, and the resulting solution is titrated with 2.50 M HCl(aq) solution. The indicator changes color, signaling that the equivalence point has been reached, after 17.0 mL of the hydrochloric acid solution has been added. (b) What is the identity of the alkali metal cation: Li+, Na+, K+, Rb+, or Cs+?

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Textbook Question

An 8.65-g sample of an unknown group 2 metal hydroxide is dissolved in 85.0 mL of water. An acid–base indicator is added and the resulting solution is titrated with 2.50 M HCl(aq) solution. The indicator changes color, signaling that the equivalence point has been reached, after 56.9 mL of the hydrochloric acid solution has been added. (b) What is the identity of the metal cation: Ca2+, Sr2+, or Ba2+?

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