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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 109c

A sample of 8.69 g of Zn1OH22 is added to 155.0 mL of 0.750 M H2SO4. (c) How many moles of ZnSO4 are present after the reaction is complete?

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Identify the chemical reaction: \( \text{Zn(OH)}_2 + \text{H}_2\text{SO}_4 \rightarrow \text{ZnSO}_4 + 2\text{H}_2\text{O} \).
Calculate the moles of \( \text{Zn(OH)}_2 \) using its molar mass: \( \text{moles of Zn(OH)}_2 = \frac{8.69 \text{ g}}{\text{molar mass of Zn(OH)}_2} \).
Calculate the moles of \( \text{H}_2\text{SO}_4 \) using its concentration and volume: \( \text{moles of H}_2\text{SO}_4 = 0.750 \text{ M} \times 0.155 \text{ L} \).
Determine the limiting reactant by comparing the mole ratio from the balanced equation.
Use the stoichiometry of the balanced equation to find the moles of \( \text{ZnSO}_4 \) produced from the limiting reactant.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions. It involves using balanced chemical equations to determine the relationships between the amounts of substances consumed and produced. In this question, stoichiometry will help us find the moles of ZnSO4 formed from the reaction between Zn(OH)2 and H2SO4.
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Molarity

Molarity is a measure of concentration defined as the number of moles of solute per liter of solution. It is crucial for determining how much of a substance is present in a given volume of solution. In this problem, the molarity of H2SO4 is given, which will be used to calculate the moles of H2SO4 available for the reaction.
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Limiting Reactant

The limiting reactant is the substance that is completely consumed in a chemical reaction, thus determining the maximum amount of product that can be formed. Identifying the limiting reactant is essential for calculating the final amounts of products, such as ZnSO4 in this case, as it dictates how much of the other reactant can react.
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Related Practice
Textbook Question

(b) An elemental analysis of the acid indicates that it is composed of 5.89% H, 70.6% C, and 23.5% O by mass. What is its molecular formula?

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Textbook Question
The discovery of hafnium, element number 72, provided a controversial episode in chemistry. G. Urbain, a French chemist, claimed in 1911 to have isolated an element number 72 from a sample of rare earth (elements 58–71) compounds. However, Niels Bohr believed that hafnium was more likely to be found along with zirconium than with the rare earths. D. Coster and G. von Hevesy, working in Bohr's laboratory in Copenhagen, showed in 1922 that element 72 was present in a sample of Norwegian zircon, an ore of zirconium. (The name hafnium comes from the Latin name for Copenhagen, Hafnia). (c) Solid zirconium dioxide, ZrO2, reacts with chlorine gas in the presence of carbon. The products of the reaction are ZrCl4 and two gases, CO2 and CO in the ratio 1:2. Write a balanced chemical equation for the reaction.
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Open Question
A 3.50 g of an alloy which contains only lead and tin is dissolved in hot HNO3. Excess sulfuric acid is added to this solution and 1.57 g of PbSO4(s) is obtained. (a) Write the net ionic equation for the formation of PbSO4.