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Ch.20 - Electrochemistry
Chapter 20, Problem 115

Hydrogen gas has the potential for use as a clean fuel in reaction with oxygen. The relevant reaction is 2 H2(g) + O2(g) → 2 H2O(l). Consider two possible ways of utilizing this reaction as an electrical energy source: (i) Hydrogen and oxygen gases are combusted and used to drive a generator, much as coal is currently used in the electric power industry; (ii) hydrogen and oxygen gases are used to generate electricity directly by using fuel cells that operate at 85 °C. Based on the analysis here, would it be more efficient to use the combustion method or the fuel-cell method to generate electrical energy from hydrogen?

Verified step by step guidance
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Step 1: Understand the chemical reaction involved. The reaction 2 H2(g) + O2(g) → 2 H2O(l) is an exothermic reaction, meaning it releases energy. This energy can be harnessed in different ways to generate electricity.
Step 2: Consider the efficiency of energy conversion in combustion. In the combustion method, hydrogen and oxygen gases are burned to produce heat, which is then used to drive a generator. This process involves multiple energy conversion steps: chemical energy to thermal energy, thermal energy to mechanical energy, and finally mechanical energy to electrical energy. Each step has inherent energy losses, typically making this method less efficient.
Step 3: Analyze the fuel cell method. Fuel cells convert chemical energy directly into electrical energy through electrochemical reactions. This direct conversion typically results in higher efficiency because it bypasses the intermediate steps of converting energy into heat and then into mechanical energy.
Step 4: Consider the operating conditions. Fuel cells operating at 85 °C are designed to optimize the electrochemical reaction efficiency. The lower operating temperature compared to combustion processes reduces energy losses associated with heat transfer and increases overall efficiency.
Step 5: Compare the overall efficiencies. Generally, fuel cells are more efficient than combustion methods because they convert chemical energy directly into electrical energy with fewer energy losses. Therefore, using fuel cells to generate electricity from hydrogen is likely to be more efficient than using the combustion method.
Related Practice
Textbook Question

Aqueous solutions of ammonia 1NH32 and bleach (active ingredient NaOCl) are sold as cleaning fluids, but bottles of both of them warn: 'Never mix ammonia and bleach, as toxic gases may be produced.' One of the toxic gases that can be produced is chloroamine, NH2Cl. (b) What is the oxidation number of chlorine in chloramine?

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Textbook Question

Aqueous solutions of ammonia 1NH32 and bleach (active ingredient NaOCl) are sold as cleaning fluids, but bottles of both of them warn: 'Never mix ammonia and bleach, as toxic gases may be produced.' One of the toxic gases that can be produced is chloroamine, NH2Cl. (e) Is N oxidized, reduced, or neither, upon the conversion of ammonia to nitrogen trichloride?

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Open Question
A voltaic cell is based on Ag+ (aq) > Ag (s) and Fe3+ (aq) > Fe2+ (aq) half-cells. Use S° values in Appendix C and the relationship between cell potential and free-energy change to predict whether the standard cell potential increases or decreases when the temperature is raised above 25 °C.
Textbook Question

Cytochrome, a complicated molecule that we will represent as CyFe2+, reacts with the air we breathe to supply energy required to synthesize adenosine triphosphate (ATP). The body uses ATP as an energy source to drive other reactions (Section 19.7). At pH 7.0 the following reduction potentials pertain to this oxidation of CyFe2+: O21g2 + 4 H+1aq2 + 4 e- ¡ 2 H2O1l2 Ered ° = +0.82 V CyFe3+1aq2 + e- ¡ CyFe2+1aq2 E°red = +0.22 V (a) What is ∆G for the oxidation of CyFe2+ by air? (b) If the synthesis of 1.00 mol of ATP from adenosine diphosphate (ADP) requires a ∆G of 37.7 kJ, how many moles of ATP are synthesized per mole of O2?

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Textbook Question

Cytochrome, a complicated molecule that we will represent as CyFe2+, reacts with the air we breathe to supply energy required to synthesize adenosine triphosphate (ATP). The body uses ATP as an energy source to drive other reactions (Section 19.7). At pH 7.0 the following reduction potentials pertain to this oxidation of CyFe2+: O21g2 + 4 H+1aq2 + 4 e- ¡ 2 H2O1l2 Ered ° = +0.8 (b) If the synthesis of 1.00 mol of ATP from adenosine diphosphate (ADP) requires a ∆G of 37.7 kJ, how many moles of ATP are synthesized per mole of O2?

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Open Question
The standard potential for the reduction of AgSCN(s) is +0.09 V. AgSCN(s) + e⁻ → Ag(s) + SCN⁻(aq). Using this value and the electrode potential for Ag⁺(aq), calculate the Ksp for AgSCN.