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Ch.19 - Chemical Thermodynamics

Chapter 19, Problem 100b

The conversion of natural gas, which is mostly methane, into products that contain two or more carbon atoms, such as ethane (C2H6), is a very important industrial chemical process. In principle, methane can be converted into ethane and hydrogen: 2 CH4(g) → C2H6(g) + H2(g) In practice, this reaction is carried out in the presence of oxygen: 2 CH4(g) + 12 O2(g) → C2H6(g) + H2O(g) (b) Is the difference in ΔG° for the two reactions due primarily to the enthalpy term (ΔH) or the entropy term (-TΔS)?

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