Chapter 17, Problem 103
The solubility-product constant for barium permanganate, Ba1MnO422, is 2.5 * 10-10. Assume that solid Ba1MnO422 is in equilibrium with a solution of KMnO4. What concentration of KMnO4 is required to establish a concentration of 2.0 * 10-8 M for the Ba2 + ion in solution?
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The solubility of CaCO3 is pH dependent. (b) Use the Kb expression for the CO32 - ion to determine the equilibrium constant for the reaction CaCO31s2 + H2O1l2 ΔCa2 + 1aq2 + HCO3-1aq2 + OH-1aq2
Tooth enamel is composed of hydroxyapatite, whose simplest formula is Ca51PO423OH, and whose corresponding Ksp = 6.8 * 10-27. As discussed in the Chemistry and Life box on page 746, fluoride in fluorinated water or in toothpaste reacts with hydroxyapatite to form fluoroapatite, Ca51PO423F, whose Ksp = 1.0 * 10-60. (a) Write the expression for the solubility-constant for hydroxyapatite and for fluoroapatite.
Calculate the solubility of Mg1OH22 in 0.50 M NH4Cl.
The solubility product constants of PbSO4 and SrSO4 are 6.3 * 10-7 and 3.2 * 10-7, respectively. What are the values of 3SO4 2 - 4, 3Pb2 + 4, and 3Sr2 + 4 in a solution at equilibrium with both substances?
The solubility product for Zn1OH22 is 3.0 * 10-16. The formation constant for the hydroxo complex, Zn1OH242 - , is 4.6 * 1017. What concentration of OH- is required to dissolve 0.015 mol of Zn1OH22 in a liter of solution?