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Ch.16 - Acid-Base Equilibria
Chapter 16, Problem 121

In many reactions, the addition of AlCl3 produces the same effect as the addition of H+. (a) Draw a Lewis structure for AlCl3 in which no atoms carry formal charges, and determine its structure using the VSEPR method. (b) What characteristic is notable about the structure in part (a) that helps us understand the acidic character of AlCl3?

Verified step by step guidance
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Draw the Lewis structure for AlCl3: Start by counting the total number of valence electrons. Aluminum (Al) has 3 valence electrons, and each chlorine (Cl) has 7 valence electrons. Since there are three chlorine atoms, the total number of valence electrons is 3 + (3 * 7) = 24.
Distribute the electrons to form bonds: Place Al in the center and arrange the three Cl atoms around it. Use a pair of electrons to form a single bond between Al and each Cl atom. This uses up 6 electrons, leaving 18 electrons to be distributed.
Complete the octets for the Cl atoms: Each Cl atom needs 8 electrons to complete its octet. Since each Cl is already bonded to Al with 2 electrons, add 6 more electrons (as lone pairs) to each Cl atom. This uses up all 18 remaining electrons.
Determine the molecular geometry using VSEPR: AlCl3 has three bonding pairs and no lone pairs on the central Al atom. According to VSEPR theory, this results in a trigonal planar geometry with bond angles of approximately 120°.
Identify the notable characteristic: The Lewis structure of AlCl3 shows that Al has only 6 electrons in its valence shell, making it electron-deficient. This electron deficiency is what gives AlCl3 its acidic character, as it can accept an electron pair from a donor, similar to how H+ acts as a Lewis acid.
Related Practice
Textbook Question
The volume of an adult's stomach ranges from about 50 mL when empty to 1 L when full. If the stomach volume is 400 mL and its contents have a pH of 2, how many moles of H+ does the stomach contain? Assuming that all the H+ comes from HCl, how many grams of sodium hydrogen carbonate will totally neutralize the stomach acid?
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Textbook Question

Atmospheric CO2 levels have risen by nearly 20% over the past 40 years from 320 ppm to 400 ppm. (a) Given that the average pH of clean, unpolluted rain today is 5.4, determine the pH of unpolluted rain 40 years ago. Assume that carbonic acid 1H2CO32 formed by the reaction of CO2 and water is the only factor influencing pH. CO21g2 + H2O1l2 Δ H2CO31aq2

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Textbook Question

At 50 °C, the ion-product constant for H2O has the value Kw = 5.48 * 10-14. (a) What is the pH of pure water at 50 °C? (b) Based on the change in Kw with temperature, predict whether ΔH is positive, negative, or zero for the autoionization reaction of water: 2 H2O1l2 Δ H3O+1aq2 + OH-1aq2

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Open Question
Cocaine is a weak organic base whose molecular formula is C17H21NO4. An aqueous solution of cocaine was found to have a pH of 8.53 and an osmotic pressure of 52.7 torr at 15 °C. Calculate the Kb for cocaine.
Open Question
The iodate ion is reduced by sulfite according to the following reaction: IO3^- (aq) + 3 SO3^2- (aq) -> I^- (aq) + 3 SO4^2- (aq). The rate of this reaction is found to be first order in IO3^-, first order in SO3^2-, and first order in H+. (b) By what factor will the rate of the reaction change if the pH is lowered from 5.00 to 3.50? Does the reaction proceed more quickly or more slowly at the lower pH? (c) By using the concepts discussed in Section 14.6, explain how the reaction can be pH-dependent even though H+ does not appear in the overall reaction.
Textbook Question
Using dissociation constants from Appendix D, determine the value for the equilibrium constant for each of the following reactions. (i) HCO3-1aq2 + OH-1aq2 ΔCO32-1aq2 + H2O1l2 (ii) NH4+1aq2 + CO32-1aq2 ΔNH31aq2 + HCO3-1aq2
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