Chapter 16, Problem 118
The volume of an adult's stomach ranges from about 50 mL when empty to 1 L when full. If the stomach volume is 400 mL and its contents have a pH of 2, how many moles of H+ does the stomach contain? Assuming that all the H+ comes from HCl, how many grams of sodium hydrogen carbonate will totally neutralize the stomach acid?
Video transcript
The following observations are made about a diprotic acid H2A: (i) A 0.10 M solution of H2A has pH = 3.30. (ii) A 0.10 M solution of the salt NaHA is acidic. Which of the following could be the value of pKa2 for H2A: (i) 3.22, (ii) 5.30, (iii) 7.47, or (iv) 9.82?
The amino acid glycine 1H2N¬CH2¬COOH2 can participate in the following equilibria in water: H2N¬CH2¬COOH + H2OΔ H2N¬CH2¬COO- + H3O+ Ka = 4.3 * 10-3 H2N¬CH2¬COOH + H2OΔ+H3N¬CH2¬COOH + OH- Kb = 6.0 * 10-5 (a) Use the values of Ka and Kb to estimate the equilibrium constant for the intramolecular proton transfer to form a zwitterion: H2N¬CH2¬COOH Δ +H3N¬CH2¬COO-
The amino acid glycine 1H2N¬CH2¬COOH2 can participate in the following equilibria in water: H2N¬CH2¬COOH + H2OΔ H2N¬CH2¬COO- + H3O+ Ka = 4.3 * 10-3 H2N¬CH2¬COOH + H2OΔ+H3N¬CH2¬COOH + OH- Kb = 6.0 * 10-5 (b) What is the pH of a 0.050 M aqueous solution of glycine?
Atmospheric CO2 levels have risen by nearly 20% over the past 40 years from 320 ppm to 400 ppm. (a) Given that the average pH of clean, unpolluted rain today is 5.4, determine the pH of unpolluted rain 40 years ago. Assume that carbonic acid 1H2CO32 formed by the reaction of CO2 and water is the only factor influencing pH. CO21g2 + H2O1l2 Δ H2CO31aq2