Chapter 15, Problem 8a
The reaction A2 + B2 ⇌ 2 AB has an equilibrium constant Kc = 1.5. The following diagrams represent reaction mixtures containing A2 molecules (red), B2 molecules (blue), and AB molecules. (a) Which reaction mixture is at equilibrium?
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When lead(IV) oxide is heated above 300°C, it decomposes according to the reaction, 2 PbO2(𝑠) ⇌ 2PbO(𝑠) + O2(𝑔). Consider the two sealed vessels of PbO2 shown here. If both vessels are heated to 400°C and allowed to come to equilibrium, which of the following statements is or are true? a. There will be less PbO2 remaining in vessel A,
When lead(IV) oxide is heated above 300°C, it decomposes according to the reaction, 2 PbO2(𝑠)⇌2PbO(𝑠)+O2(𝑔). Consider the two sealed vessels of PbO2 shown here. If both vessels are heated to 400°C and allowed to come to equilibrium, which of the following statements is or are true?
b. There will be less PbO2 remaining in vessel B,
When lead(IV) oxide is heated above 300°C, it decomposes according to the reaction, 2 PbO2(𝑠) ⇌ 2PbO(𝑠) + O2(𝑔). Consider the two sealed vessels of PbO2 shown here. If both vessels are heated to 400°C and allowed to come to equilibrium, which of the following statements is or are true? (c) The amount of PbO2 remaining in each vessel will be the same. [Find more in Section 15.4]
The diagram shown here represents the equilibrium state for the reaction A2(𝑔) + 2B(𝑔) ⇌ 2AB(𝑔). (a) Assuming the volume is 2 L, calculate the equilibrium constant 𝐾𝑐 for the reaction.
Suppose that the gas-phase reactions A → B and B → A are both elementary reactions with rate constants of 4.7×10−3 s−1 and 5.8×10−1 s−1, respectively. (b) Which is greater at equilibrium, the partial pressure of A or the partial pressure of B?
The equilibrium constant for the dissociation of molecular iodine, I2(𝑔) ⇌ 2 I(𝑔), at 800 K is 𝐾𝑐 = 3.1×10−5. (b) Assuming both forward and reverse reactions are elementary reactions, which reaction has the larger rate constant, the forward or the reverse reaction?