At 900 K, the following reaction has πΎπ = 0.345: 2 SO2(π) + O2(π) β 2 SO3(π) In an equilibrium mixture the partial pressures of SO2 and O2 are 0.135 atm and 0.455 atm, respectively. What is the equilibrium partial pressure of SO3 in the mixture?
At 373 K, πΎπ = 0.416 for the equilibrium 2 NOBr(π) β 2 NO(π) + Br2(π) If the pressures of NOBr(π) and NO(π) are equal, what is the equilibrium pressure of Br2(π)?
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Key Concepts
Equilibrium Constant (Kp)
Partial Pressure
Le Chatelier's Principle
At 2000Β°C, the equilibrium constant for the reaction 2 NO(π) β N2(π) + O2(π) is πΎπ = 2.4Γ103. If the initial concentration of NO is 0.175 M, what are the equilibrium concentrations of NO, N2, and O2?
For the equilibrium Br2(π) + Cl2(π) β 2 BrCl(π) at 400 K, πΎπ = 7.0. If 0.25 mol of Br2 and 0.55 mol of Cl2 are introduced into a 3.0-L container at 400 K, what will be the equilibrium concentrations of Br2, Cl2, and BrCl?
At 218Β°C, πΎπ = 1.2Γ10β4 for the equilibrium NH4SH(π ) β NH3(π) + H2S(π) Calculate the equilibrium concentrations of NH3 and H2S if a sample of solid NH4SH is placed in a closed vessel at 218Β°C and decomposes until equilibrium is reached.
At 80Β°C, πΎπ = 1.87Γ10β3 for the reaction PH3BCl3(π ) β PH3(π) + BCl3(π) (a) Calculate the equilibrium concentrations of PH3 and BCl3 if a solid sample of PH3BCl3 is placed in a closed vessel at 80Β°C and decomposes until equilibrium is reached.
At 80Β°C, πΎπ = 1.87Γ10β3 for the reaction PH3BCl3(π ) β PH3(π) + BCl3(π) (a) Calculate the equilibrium concentrations of PH3 and BCl3 if a solid sample of PH3BCl3 is placed in a closed vessel at 80Β°C and decomposes until equilibrium is reached. (b) If the flask has a volume of 0.250 L, what is the minimum mass of PH3BCl3(π ) that must be added to the flask to achieve equilibrium?