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Ch.15 - Chemical Equilibrium

Chapter 15, Problem 53

At 373 K, 𝐾𝑝 = 0.416 for the equilibrium 2 NOBr(𝑔) β‡Œ 2 NO(𝑔) + Br2(𝑔) If the pressures of NOBr(𝑔) and NO(𝑔) are equal, what is the equilibrium pressure of Br2(𝑔)?

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Hello everyone today. We are being given the following problem and asks to solve for it. It says the equilibrium constant K. C. Of the following reaction at 25 degrees Celsius is 8.6 times 10 to the negative fifth in a saturated solution of this magnesium oxalate, calculate the the equilibrium concentrations of both magnesium and oxalic acid obsolete. So the first thing they don't want to do is we want to know our K. C. Expression So we have Casey and when right in this case the expression we're going to write the concentration of our products and the numerator over the concentration of our reactant in the denominator. And so we're also going to only want to pay attention to gasses. So with Casey expression you only pay attention to the gasses in writing this out. We're gonna start with our first reactant which is magnesium. So we're going to have MG two plus in brackets. And we're going to multiply the second reactant which is oxalate, C 2042 - also in Brackets. And since we said that we only pay attention to gasses and not solids, we are not going to write our magnesium oxalate in this case the expression and so continue on to this. Since we don't know the concentrations of magnesium or oxalate, we can simply substitute them for X. So we're going to have X times X. And then we plug in our K. C. Value of 8.6 times 10 to the negative fifth. That will equal X squared When we square both sides, we get that X. is equal to 9.3 times 10 to the negative third, and that is also going to be equal to our concentrations of magnesium two plus as well as our concentration of oxalate. I hope this helped, and until next time.
Related Practice
Textbook Question

At 900 K, the following reaction has 𝐾𝑝 = 0.345: 2 SO2(𝑔) + O2(𝑔) β‡Œ 2 SO3(𝑔) In an equilibrium mixture the partial pressures of SO2 and O2 are 0.135 atm and 0.455 atm, respectively. What is the equilibrium partial pressure of SO3 in the mixture?

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Textbook Question

At 2000Β°C, the equilibrium constant for the reaction 2 NO(𝑔) β‡Œ N2(𝑔) + O2(𝑔) is 𝐾𝑐 = 2.4Γ—103. If the initial concentration of NO is 0.175 M, what are the equilibrium concentrations of NO, N2, and O2?

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Textbook Question

For the equilibrium Br2(𝑔) + Cl2(𝑔) β‡Œ 2 BrCl(𝑔) at 400 K, 𝐾𝑐 = 7.0. If 0.25 mol of Br2 and 0.55 mol of Cl2 are introduced into a 3.0-L container at 400 K, what will be the equilibrium concentrations of Br2, Cl2, and BrCl?

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Textbook Question

At 218Β°C, 𝐾𝑐 = 1.2Γ—10βˆ’4 for the equilibrium NH4SH(𝑠) β‡Œ NH3(𝑔) + H2S(𝑔) Calculate the equilibrium concentrations of NH3 and H2S if a sample of solid NH4SH is placed in a closed vessel at 218Β°C and decomposes until equilibrium is reached.

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Textbook Question

At 80Β°C, 𝐾𝑐 = 1.87Γ—10βˆ’3 for the reaction PH3BCl3(𝑠) β‡Œ PH3(𝑔) + BCl3(𝑔) (a) Calculate the equilibrium concentrations of PH3 and BCl3 if a solid sample of PH3BCl3 is placed in a closed vessel at 80Β°C and decomposes until equilibrium is reached.

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Textbook Question

At 80Β°C, 𝐾𝑐 = 1.87Γ—10βˆ’3 for the reaction PH3BCl3(𝑠) β‡Œ PH3(𝑔) + BCl3(𝑔) (a) Calculate the equilibrium concentrations of PH3 and BCl3 if a solid sample of PH3BCl3 is placed in a closed vessel at 80Β°C and decomposes until equilibrium is reached. (b) If the flask has a volume of 0.250 L, what is the minimum mass of PH3BCl3(𝑠) that must be added to the flask to achieve equilibrium?

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