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Ch.15 - Chemical Equilibrium
Chapter 15, Problem 51

At 2000Β°C, the equilibrium constant for the reaction 2 NO(𝑔) β‡Œ N2(𝑔) + O2(𝑔) is 𝐾𝑐 = 2.4Γ—103. If the initial concentration of NO is 0.175 M, what are the equilibrium concentrations of NO, N2, and O2?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Equilibrium Constant (Kc)

The equilibrium constant (Kc) is a numerical value that expresses the ratio of the concentrations of products to reactants at equilibrium for a given reaction at a specific temperature. For the reaction 2 NO(g) β‡Œ N2(g) + O2(g), Kc = [N2][O2]/[NO]^2. A larger Kc value indicates that products are favored at equilibrium, while a smaller Kc suggests that reactants are favored.
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ICE Table

An ICE table (Initial, Change, Equilibrium) is a tool used to organize the concentrations of reactants and products in a chemical reaction at different stages. It helps in calculating the changes in concentration as the system reaches equilibrium. By filling in the initial concentrations, the changes that occur, and the equilibrium concentrations, one can systematically determine the equilibrium state of the reaction.
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Stoichiometry

Stoichiometry involves the quantitative relationships between the amounts of reactants and products in a chemical reaction, based on the balanced chemical equation. In the reaction 2 NO(g) β‡Œ N2(g) + O2(g), stoichiometry allows us to relate the change in concentration of NO to the formation of N2 and O2, using the coefficients from the balanced equation to determine how much of each species is present at equilibrium.
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Related Practice
Textbook Question

(b) At the start of a certain reaction, only reactants are present; no products have been formed. What is the value of Qc at this point in the reaction?

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Textbook Question

At 100Β°C, the equilibrium constant for the reaction COCl2(𝑔) β‡Œ CO(𝑔) + Cl2(𝑔) has the value 𝐾𝑐 = 2.19Γ—10βˆ’10. Are the following mixtures of COCl2, CO, and Cl2 at 100Β°C at equilibrium? If not, indicate the direction that the reaction must proceed to achieve equilibrium. (a) [COCl2] = 2.00Γ—10βˆ’3 𝑀, [CO] = 3.3Γ—10βˆ’6 𝑀, [Cl2] = 6.62Γ—10βˆ’6𝑀

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Textbook Question

At 900 K, the following reaction has 𝐾𝑝 = 0.345: 2 SO2(𝑔) + O2(𝑔) β‡Œ 2 SO3(𝑔) In an equilibrium mixture the partial pressures of SO2 and O2 are 0.135 atm and 0.455 atm, respectively. What is the equilibrium partial pressure of SO3 in the mixture?

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Textbook Question

For the equilibrium Br2(𝑔) + Cl2(𝑔) β‡Œ 2 BrCl(𝑔) at 400 K, 𝐾𝑐 = 7.0. If 0.25 mol of Br2 and 0.55 mol of Cl2 are introduced into a 3.0-L container at 400 K, what will be the equilibrium concentrations of Br2, Cl2, and BrCl?

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Textbook Question

At 373 K, 𝐾𝑝 = 0.416 for the equilibrium 2 NOBr(𝑔) β‡Œ 2 NO(𝑔) + Br2(𝑔) If the pressures of NOBr(𝑔) and NO(𝑔) are equal, what is the equilibrium pressure of Br2(𝑔)?

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Textbook Question

At 218Β°C, 𝐾𝑐 = 1.2Γ—10βˆ’4 for the equilibrium NH4SH(𝑠) β‡Œ NH3(𝑔) + H2S(𝑔) Calculate the equilibrium concentrations of NH3 and H2S if a sample of solid NH4SH is placed in a closed vessel at 218Β°C and decomposes until equilibrium is reached.

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