Chapter 14, Problem 70c
Consider the following energy profile.
(c) Which step is rate limiting?
Video transcript
(c) Which step is the fastest?
Consider the following energy profile.
(a) How many elementary reactions are in the reaction mechanism?
Consider the following energy profile.
(b) How many intermediates are formed in the reaction?
The decomposition of hydrogen peroxide is catalyzed by iodide ion. The catalyzed reaction is thought to proceed by a two-step mechanism:
H2O2(aq) + I-(aq) → H2O(l) + IO-(aq) (slow)
IO-(aq) + H2O2(aq) → H2O(l) + O2(g) + I-(aq) (fast)
(a) Write the chemical equation for the overall process.
The decomposition of hydrogen peroxide is catalyzed by iodide ion. The catalyzed reaction is thought to proceed by a two-step mechanism:
H2O2(aq) + I-(aq) → H2O(l) + IO-(aq) (slow)
IO-(aq) + H2O2(aq) → H2O(l) + O2(g) + I-(aq) (fast)
(b) Identify the intermediate, if any, in the mechanism.
The decomposition of hydrogen peroxide is catalyzed by iodide ion. The catalyzed reaction is thought to proceed by a two-step mechanism:
H2O2(aq) + I-(aq) → H2O(l) + IO-(aq) (slow)
IO-(aq) + H2O2(aq) → H2O(l) + O2(g) + I-(aq) (fast)
(c) Assuming that the first step of the mechanism is rate determining, predict the rate law for the overall process.