Skip to main content
Ch.14 - Chemical Kinetics
Chapter 14, Problem 72a

The decomposition of hydrogen peroxide is catalyzed by iodide ion. The catalyzed reaction is thought to proceed by a two-step mechanism:
H2O2(aq) + I-(aq) → H2O(l) + IO-(aq) (slow)
IO-(aq) + H2O2(aq) → H2O(l) + O2(g) + I-(aq) (fast)
(a) Write the chemical equation for the overall process.

Verified Solution

Video duration:
2m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Chemical Equations

A chemical equation represents a chemical reaction using symbols and formulas. It shows the reactants on the left side and the products on the right, separated by an arrow indicating the direction of the reaction. Balancing the equation is crucial to obey the law of conservation of mass, ensuring that the number of atoms for each element is the same on both sides.
Recommended video:
Guided course
01:32
Balancing Chemical Equations

Reaction Mechanisms

A reaction mechanism describes the step-by-step sequence of elementary reactions by which overall chemical change occurs. Understanding the mechanism helps in identifying the rate-determining step, which is the slowest step that controls the speed of the overall reaction. In this case, the two-step mechanism illustrates how iodide ion facilitates the decomposition of hydrogen peroxide.
Recommended video:
Guided course
03:06
Reaction Mechanism Overview

Catalysis

Catalysis involves the acceleration of a chemical reaction by a substance called a catalyst, which is not consumed in the reaction. Catalysts work by providing an alternative pathway with a lower activation energy for the reaction. In the given question, iodide ion acts as a catalyst, facilitating the breakdown of hydrogen peroxide into water and oxygen without being permanently altered.
Recommended video:
Guided course
01:59
Catalyzed vs. Uncatalyzed Reactions