Chapter 14, Problem 59
Based on their activation energies and energy changes and assuming that all collision factors are the same, rank the following reactions from slowest to fastest. (a) Ea = 45 kJ>mol; E = -25 kJ>mol (b) Ea = 35 kJ>mol; E = -10 kJ>mol (c) Ea = 55 kJ>mol; E = 10 kJ>mol
Video transcript
Indicate whether each statement is true or false. (a) If you measure the rate constant for a reaction at different temperatures, you can calculate the overall enthalpy change for the reaction.
Indicate whether each statement is true or false. (b) Exothermic reactions are faster than endothermic reactions.
Indicate whether each statement is true or false. (c) If you double the temperature for a reaction, you cut the activation energy in half.
The temperature dependence of the rate constant for a reaction is tabulated as follows: Temperature (K) k 1M 1 s1 2 600 0.028 650 0.22 700 1.3 750 6.0 800 23 Calculate Ea and A.
(b) What is the difference between a unimolecular and a bimolecular elementary reaction?
What is the molecularity of each of the following elementary reactions? Write the rate law for each. (a) Cl2(g) → 2 Cl(g)